连续流微反应器中的液相氧化化学。
Liquid phase oxidation chemistry in continuous-flow microreactors.
机构信息
Department of Chemical Engineering and Chemistry, Micro Flow Chemistry & Process Technology, Eindhoven University of Technology, Den Dolech 2, 5612 AZ Eindhoven, The Netherlands.
Departamento de Quimica Organica, Universidad de Cordoba, Edificio Marie Curie (C-3), Campus de Rabanales, Ctra. Nnal. IV-A, Km 396, E14014 Cordoba, Spain.
出版信息
Chem Soc Rev. 2016 Jan 7;45(1):83-117. doi: 10.1039/c5cs00447k.
Continuous-flow liquid phase oxidation chemistry in microreactors receives a lot of attention as the reactor provides enhanced heat and mass transfer characteristics, safe use of hazardous oxidants, high interfacial areas, and scale-up potential. In this review, an up-to-date overview of both technological and chemical aspects of liquid phase oxidation chemistry in continuous-flow microreactors is given. A description of mass and heat transfer phenomena is provided and fundamental principles are deduced which can be used to make a judicious choice for a suitable reactor. In addition, the safety aspects of continuous-flow technology are discussed. Next, oxidation chemistry in flow is discussed, including the use of oxygen, hydrogen peroxide, ozone and other oxidants in flow. Finally, the scale-up potential for continuous-flow reactors is described.
连续流液相氧化反应在微反应器中受到广泛关注，因为其具有增强的传热和传质特性、安全使用危险氧化剂、高界面面积和扩大规模的潜力。在这篇综述中，对连续流微反应器中液相氧化反应的技术和化学方面进行了最新的概述。提供了对传质和传热现象的描述，并推导出了可以用来明智地选择合适反应器的基本原理。此外，还讨论了连续流技术的安全方面。接下来，讨论了流动中的氧化化学，包括在流动中使用氧气、过氧化氢、臭氧和其他氧化剂。最后，描述了连续流反应器的扩大规模潜力。
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