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基于有机材料的汞荧光传感器:最新进展简述。

Organic Material Based Fluorescent Sensor for Hg: a Brief Review on Recent Development.

机构信息

Department of Chemistry, University of Sargodha, Sub-campus Mianwali, Pakistan.

Department of Biochemistry and Biotechnology (Baghdad-ul-Jadeed Campus), The Islamia University of Bahawalpur, Bahawalpur, 63100, Pakistan.

出版信息

J Fluoresc. 2017 Jan;27(1):31-58. doi: 10.1007/s10895-016-1933-x. Epub 2016 Sep 19.

Abstract

Due to the deleterious effects of mercury on human health and natural ecosystems, high reactivity, non-degradability, extreme volatility and relative water and tissue solubility, it would consider as one of the most toxic environmental pollutants among the transition metals. In the present investigation, we have tried to summarized the several organic material based fluorescent sensor including rhodamine, boron-dipyrromethene (BODIPYs), thiourea, crown-ether, coumarine, squaraines, pyrene, imidazole, triazole, anthracene, dansyl, naphthalenedimide/ naphthalene/ naphthalimide, naphthyridine, iridium (III) complexes, polymeric materials, cyclodextrin, phthalic anhydride, indole, calix [4]arene, chromenone, 1,8-naphthalimides, lysine, styrylindolium, phenothiazine, thiocarbonyl quinacridone, oxadiazole, triphenylamine-triazines, tetraphenylethene, peptidyl and semicarbazone for the trace mercury detection in the aqueous, aqueous-organic and cellular media. The present review provides a brief look over the previous development in the organic material based fluorescent sensor for mercuric ion detection. Furthermore, the ligand-metal binding stoichiometry, binding/association/dissociation constants and the detection limit by the receptors have been particularly highlighted which might be useful for the future design and development of more sensitive and robust fluorescent chemosensor/chemodosimeter for the mercuric ion detection. Graphical Abstract Dummy.

摘要

由于汞对人类健康和自然生态系统的有害影响,高反应性、不可降解性、极端挥发性以及相对水和组织溶解度,它被认为是过渡金属中最具毒性的环境污染物之一。在本研究中,我们试图总结了几种基于有机材料的荧光传感器,包括罗丹明、硼二吡咯甲烷(BODIPYs)、硫脲、冠醚、香豆素、方酸、芘、咪唑、三唑、蒽、丹磺酰基、萘二酰亚胺/萘/萘酰亚胺、萘啶、铱(III)配合物、聚合物材料、环糊精、邻苯二甲酸酐、吲哚、杯[4]芳烃、色酮、1,8-萘酰亚胺、赖氨酸、苯乙烯吲哚𬭩、吩噻嗪、硫代羰基喹吖啶酮、恶二唑、三苯基胺-三嗪、四苯乙烯、肽基和半缩醛,用于痕量汞在水、水-有机和细胞介质中的检测。本综述简要回顾了基于有机材料的荧光传感器在汞离子检测方面的最新进展。此外,还特别强调了配体-金属结合化学计量比、结合/缔合/解离常数以及受体的检测限,这对于未来设计和开发更灵敏、更稳健的荧光化学传感器/化学计量计以用于汞离子检测可能是有用的。

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