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超轻量电纺纤维素海绵,对有机化合物具有超高吸收容量。

Ultralight electrospun cellulose sponge with super-high capacity on absorption of organic compounds.

机构信息

Program of Biomedical Engineering, South Dakota School of Mines and Technology, Rapid City, SD 57701, USA.

Program of Biomedical Engineering, South Dakota School of Mines and Technology, Rapid City, SD 57701, USA; Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China.

出版信息

Carbohydr Polym. 2018 Jan 1;179:164-172. doi: 10.1016/j.carbpol.2017.09.086. Epub 2017 Sep 28.

Abstract

Three-dimensional, cost-effective, and renewable/recyclable absorbent materials with high capacities on absorption of organic compounds are urgently in demand. Herein, a facile while innovative approach is reported to develop ultralight electrospun cellulose sponge (UECS). The prepared UECS exhibits super-high absorption capacity (up to 232 times of its own weight) towards absorption of organic compounds due to high porosity (99.57%), low density (6.45mg/cm), and hydrophobic surface feature (with water contact angle of 141.2°). Furthermore, the UECS is mechanically robust thus can be readily cut into different shapes; and it also possesses excellent stability against various organic compounds. Intriguingly, upon absorption of an organic compound, the shape-stable UECS organic gel can be formed. Hence, the developed UECS would be promising as environmental friendly absorbent on high-performance separation of organic compounds from aqueous systems; while the UECS organic gel could be utilized for the applications such as drug delivery and sensor.

摘要

具有三维结构、成本效益高且可再生/可回收的高容量有机化合物吸收材料是迫切需要的。在此,报道了一种简便而创新的方法来开发超轻量静电纺丝纤维素海绵(UECS)。由于高孔隙率(99.57%)、低密度(6.45mg/cm)和疏水性表面特性(水接触角为 141.2°),所制备的 UECS 对有机化合物的吸收具有超高的吸收能力(高达自身重量的 232 倍)。此外,UECS 机械强度高,可轻易切割成不同形状;并且对各种有机化合物也具有出色的稳定性。有趣的是,在吸收有机化合物后,可形成形状稳定的 UECS 有机凝胶。因此,所开发的 UECS 有望成为从水相体系中高效分离有机化合物的环保型吸收剂;而 UECS 有机凝胶可用于药物输送和传感器等应用。

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