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一种通过自组装方法合成的环保型介孔二氧化硅颗粒,其与WSe-石墨烯-TiO复合用于光催化染料分解和制氢。

An eco-friendly synthesized mesoporous-silica particle combined with WSe-graphene-TiO by self-assembled method for photocatalytic dye decomposition and hydrogen production.

作者信息

Zhu Lei, Nguyen Dinh Cung Tien, Woo Jung-Hun, Zhang Qinfang, Cho Kwang Youn, Oh Won-Chun

机构信息

Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng, 224051, China.

Department of Advanced Materials Science & Engineering, Hanseo University, Seosan, 31962, Korea.

出版信息

Sci Rep. 2018 Aug 24;8(1):12759. doi: 10.1038/s41598-018-31188-w.

Abstract

To address the limitations of titanium dioxide (TiO) and expand the applicability of the photocatalytic activity of TiO,WSe and silica, an eco-friendly, self-assembled method for combining a silica precursor with a WSe-graphene-TiO composite with cetyltrimethylammonium bromide (CTAB) as surface active agents is proposed. Firstly, for the main target, the photocatalytic degradation of organic dye solutions with different initial pH levels and catalyst dosages under visible light irradiation was surveyed. The as-synthesized sample exhibited highly efficient photocatalytic effects for the treatment of the SO dye solution in the optimal conditions of this study, which included a solution with a pH level of 11 and 0.05-gram dosage of the catalyst. Secondly, previous photocatalytic hydrogen production studies reported markedly better outcomes with SiO/WSe-graphene-TiO than with the binary WSe-graphene and ternary WSe-graphene-TiO composites under ambient conditions with and without 20% methanol sacrificing reagents. The SiO/WSe-graphene-TiO composite is promising to become a potential candidate for photocatalytic performance that performs excellently as well as offer an efficient heterosystem for hydrogen production.

摘要

为了解决二氧化钛(TiO)的局限性并扩大TiO、WSe和二氧化硅光催化活性的适用性,提出了一种以十六烷基三甲基溴化铵(CTAB)为表面活性剂,将二氧化硅前驱体与WSe-石墨烯-TiO复合材料相结合的环保自组装方法。首先,针对主要目标,研究了在可见光照射下,不同初始pH值和催化剂用量的有机染料溶液的光催化降解情况。在本研究的最佳条件下,即pH值为11的溶液和0.05克催化剂用量的条件下,合成的样品对SO染料溶液的处理表现出高效的光催化效果。其次,先前的光催化产氢研究报告称,在有和没有20%甲醇牺牲试剂的环境条件下,SiO/WSe-石墨烯-TiO的产氢效果明显优于二元WSe-石墨烯和三元WSe-石墨烯-TiO复合材料。SiO/WSe-石墨烯-TiO复合材料有望成为具有优异光催化性能的潜在候选材料,并为产氢提供一个高效的异质体系。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/74f7/6109040/9afa1831de30/41598_2018_31188_Fig1_HTML.jpg

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