Enhanced photocatalytic activity of rGO/TiO for the decomposition of formaldehyde under visible light irradiation.

Due to the low concentration of indoor air contaminants, photocatalytic technology shows low efficiency for indoor air purification. The application of TiO for photocatalytic removal of formaldehyde is limited, because TiO can only absorb ultraviolet (UV) light. Immobilization of TiO nanoparticles on the surface of graphene can improve the visible light photocatalytic activity and the adsorption capacity. In this study, rGO (reduced graphene oxide)/TiO was synthesized through a hydrothermal method using titanium tetrabutoxide and graphene oxide as precursors, and was used for the degradation of low concentration formaldehyde in indoor air under visible light illumination. Characterization of the crystalline structure and morphology of rGO/TiO revealed that most GO was reduced to rGO during the hydrothermal treatment, and anatase TiO nanoparticles (with particle size of 15-30nm) were dispersed well on the surface of the rGO sheets. rGO/TiO exhibited excellent photocatalytic activity for degradation of formaldehyde in indoor air and this can be attributed to the role of rGO, which can act as the electron sink and transporter for separating photo-generated electron-hole pairs through interfacial charge transfer. Furthermore, rGO could adsorb formaldehyde molecules from air to produce a high concentration of formaldehyde on the surface of rGO/TiO. Under visible light irradiation for 240min, the concentration of formaldehyde could be reduced to 58.5ppbV. rGO/TiO showed excellent moisture-resistance behavior, and after five cycles, rGO/TiO maintained high photocatalytic activity for the removal of formaldehyde (84.6%). This work suggests that the synthesized rGO/TiO is a promising photocatalyst for indoor formaldehyde removal.