环丙烷衍生物的氧化自由基开环/环化反应
Oxidative radical ring-opening/cyclization of cyclopropane derivatives.
作者信息
Liu Yu, Wang Qiao-Lin, Chen Zan, Zhou Cong-Shan, Xiong Bi-Quan, Zhang Pan-Liang, Yang Chang-An, Zhou Quan
机构信息
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, P. R. China.
出版信息
Beilstein J Org Chem. 2019 Jan 28;15:256-278. doi: 10.3762/bjoc.15.23. eCollection 2019.
The ring-opening/cyclization of cyclopropane derivatives has drawn great attention in the past several decades. In this review, recent efforts in the development of oxidative radical ring-opening/cyclization of cyclopropane derivatives, including methylenecyclopropanes, cyclopropyl olefins and cyclopropanols, are described. We hope this review will be of sufficient interest for the scientific community to further advance the application of oxidative radical strategies in the ring-opening/cyclization of cyclopropane derivatives.
在过去几十年中，环丙烷衍生物的开环/环化反应备受关注。在这篇综述中，描述了包括亚甲基环丙烷、环丙基烯烃和环丙醇在内的环丙烷衍生物氧化自由基开环/环化反应开发方面的最新研究成果。我们希望这篇综述能引起科学界的足够兴趣，以进一步推动氧化自由基策略在环丙烷衍生物开环/环化反应中的应用。
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