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利用大理石污泥废料制造环保材料:应用循环经济原则。

Use of marble sludge waste in the manufacture of eco-friendly materials: applying the principles of the Circular Economy.

机构信息

Department of Chemical, Environmental and Materials Engineering, Technological Scientific Campus of Linares, University of Jaén, 23700, Linares, Jaén, Spain.

出版信息

Environ Sci Pollut Res Int. 2019 Dec;26(35):35399-35410. doi: 10.1007/s11356-019-05098-x. Epub 2019 Apr 18.

Abstract

The marble industry generates enormous amounts of waste every year, whose incorrect management can lead to environmental problems. The Circular Economy model can provide an effective solution to this issue, an aspect that has been addressed in this research. The suitability of a marble sludge generated in the ornamental rock industry of Andalusia (Spain) has been assessed as raw material in ceramic bricks. Mixtures containing a clayey base and 0, 2.5, 5, 7.5, and 10 wt% of marble powder have been shaped into 60 × 30 × 10-mm prismatic specimens and sintered at 950 °C in a muffle. The main technological properties of the bricks related to color, shrinkage, porosity, water absorption, suction, and compressive strength have been determined. The addition of marble sludge has fostered the development of a lighter color, together with a significant increase of the open porosity. This aspect has implied, on the one hand, higher water absorption and suction results and, on the other hand, a decrease of the density and the mechanical strength. The correlations obtained after applying Shapiro-Wilk normality tests and r Pearson coefficients endorse the clear relationship between the addition of marble powder and the abovementioned effects on the technological properties of the sintered bricks. All the measured properties fully meet the brick standardized requirements, which would indicate that the recycling of marble wastes could be a promising alternative to obtain eco-friendly lightweight ceramic materials.

摘要

大理石行业每年产生大量的废物,如果管理不当,可能会导致环境问题。循环经济模式可以为这个问题提供一个有效的解决方案,本研究就探讨了这一方面。评估了西班牙安达卢西亚(Spain)装饰石材行业产生的大理石污泥作为陶瓷砖原料的适用性。将含有粘土基础的混合物和 0、2.5、5、7.5 和 10wt%的大理石粉末成型为 60×30×10-mm 的棱柱形试件,并在马弗炉中 950°C 下烧结。确定了与颜色、收缩、孔隙率、吸水率、吸湿性和抗压强度有关的砖的主要技术性能。大理石污泥的添加促进了颜色的变浅,同时显著增加了开口孔隙率。这一方面意味着吸水率和吸湿性的结果更高,另一方面则意味着密度和机械强度的降低。应用 Shapiro-Wilk 正态性检验和 r Pearson 系数后得到的相关性证实了大理石粉末的添加与烧结砖的上述技术性能之间的明显关系。所有测量的性能都完全符合砖的标准要求,这表明回收大理石废料可能是获得环保型轻质陶瓷材料的有前途的替代方案。

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