Department of Chemical Engineering, Universiti Teknologi PETRONAS, 32610, Bandar Seri Iskandar, Perak, Malaysia.
Department of Chemical Engineering, Universiti Teknologi PETRONAS, 32610, Bandar Seri Iskandar, Perak, Malaysia; Center for Biofuel and Biochemical Research (CBBR), Institute of Self-Sustainable Building, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak, 32610, Malaysia.
J Environ Manage. 2020 Jan 15;254:109797. doi: 10.1016/j.jenvman.2019.109797. Epub 2019 Nov 12.
The pollution of the world's water resources is a growing issue which requires remediation. Surfactants used in many domestic and industrial applications are one of the emerging contaminants that require immediate attention. Treating water contaminated with surfactants using adsorption provides better performance when compared to other techniques. A variety of materials have been developed for adsorbing surfactants. Activated carbon is the most suitable adsorbent for removing surfactants but is expensive to synthesize and difficult to regenerate. Therefore, a variety of new adsorbents such as zeolites, nanomaterials, resins, biomaterials and clays have been developed as alternatives. The developed adsorbents are promising but considerable research is still required to develop highly efficient, economical, environment friendly and sustainable adsorbents to replace activated carbon. This paper critically reviews the characteristics of adsorbents, the performance of adsorbents, kinetics, isotherms and thermodynamics, mechanisms of adsorption, regeneration of adsorbents and future perspectives in the adsorption of surfactants. Developing novel adsorbents, testing adsorbents in real wastewaters and recycling the adsorbents are required in future studies in the removal of surfactants.
世界水资源污染是一个日益严重的问题,需要加以治理。表面活性剂是许多家庭和工业应用中使用的一种新兴污染物,需要立即引起重视。与其他技术相比,用吸附法处理含表面活性剂的水具有更好的性能。已经开发出多种材料来吸附表面活性剂。活性炭是去除表面活性剂最理想的吸附剂,但合成成本高,再生困难。因此,开发了沸石、纳米材料、树脂、生物材料和粘土等各种新型吸附剂作为替代品。这些开发出的吸附剂很有前景,但仍需要大量研究来开发高效、经济、环保和可持续的吸附剂,以替代活性炭。本文批判性地综述了吸附剂的特性、吸附剂的性能、动力学、吸附等温线和热力学、吸附机理、吸附剂的再生以及表面活性剂吸附的未来展望。在未来的研究中,需要开发新型吸附剂,在实际废水中测试吸附剂,并对吸附剂进行回收,以去除表面活性剂。