State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Textiles, Donghua University, Shanghai, 201620, China.
Innovation Center for Textile Science and Technology, Donghua University, Shanghai, 200051, China.
Adv Mater. 2020 Jul;32(29):e2002361. doi: 10.1002/adma.202002361. Epub 2020 Jun 8.
Particulate matter (PM) pollution has become a serious public health issue, especially with outbreaks of emerging infectious diseases. However, most present filters are bulky, opaque, and show low-efficiency PM /pathogen interception and inevitable trade-off between PM removal and air permeability. Here, a unique electrospraying-netting technique is used to create spider-web-inspired network generator (SWING) air filters. Manipulation of the dynamic of the Taylor cone and phase separation of its ejected droplets enable the generation of 2D self-charging nanostructured networks on a large scale. The resultant SWING filters show exceptional long-range electrostatic property driven by aeolian vibration, enabling self-sustained PM adhesion. Combined with their Steiner-tree-structured pores (size 200-300 nm) consisting of nanowires (diameter 12 nm), the SWING filters exhibit high efficiency (>99.995% PM removal), low air resistance (<0.09% atmosphere pressure), high transparency (>82%), and remarkable bioprotective activity for biohazard pathogens. This work may shed light on designing new fibrous materials for environmental and energy applications.
颗粒物 (PM) 污染已成为严重的公共卫生问题,尤其是在新发传染病爆发时。然而,目前大多数的过滤器体积庞大、不透明,对 PM/病原体的截留效率低,且在 PM 去除率和透气性之间不可避免地存在权衡。在这里,我们使用独特的静电纺丝网技术来制造仿蛛网结构的网络生成器 (SWING) 空气过滤器。通过控制泰勒锥的动力学和喷射液滴的相分离,可以在较大范围内生成二维自充电纳米结构网络。所得的 SWING 过滤器具有出色的长程静电特性,能够在风力振动的作用下实现自维持的 PM 吸附。此外,SWING 过滤器的 Steiner 树状结构的孔(尺寸为 200-300nm)由纳米线(直径 12nm)组成,因此它具有高效(>99.995%的 PM 去除率)、低空气阻力(<0.09%大气压)、高透明度(>82%)和对生物危害病原体的显著防护性能。这项工作可能为设计用于环境和能源应用的新型纤维材料提供思路。