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用于高效截留空气中纳米颗粒的可生物降解的醋酸纤维素/壳聚糖共混静电纺纳米纤维。

Biodegradable CA/CPB electrospun nanofibers for efficient retention of airborne nanoparticles.

作者信息

de Almeida Daniela Sanches, Martins Leila Droprinchinski, Muniz Edvani Curti, Rudke Anderson Paulo, Squizzato Rafaela, Beal Alexandra, de Souza Paulo Ricardo, Bonfim Daniela Patrícia Freire, Aguiar Mônica Lopes, Gimenes Marcelino Luiz

机构信息

State University of Maringá, Av. Colombo, 5790 - Vila Esperança, Maringá, PR, 87020-900, Brazil.

Federal University of Technology - Paraná, Av. Dos Pioneiros, 3131, Londrina, PR, 86036-370, Brazil.

出版信息

Process Saf Environ Prot. 2020 Dec;144:177-185. doi: 10.1016/j.psep.2020.07.024. Epub 2020 Jul 17.

Abstract

The increase of the industrialization process brought the growth of pollutant emissions into the atmosphere. At the same time, the demand for advances in aerosol filtration is evolving towards more sustainable technologies. Electrospinning is gaining notoriety, once it enables to produce polymeric nanofibers with different additives and also the obtaining of small pore sizes and fiber diameters; desirable features for air filtration materials. Therefore, this work aims to evaluate the filtration performance of cellulose acetate (CA) nanofibers and cationic surfactant cetylpyridinium bromide (CPB) produced by electrospinning technique for retention of aerosol nanoparticles. The pressure drop and collection efficiency measurements of sodium chloride (NaCl) aerosol particles (diameters from 7 to 300 nm) were performed using Scanning Mobility Particle Sizer (SMPS). The average diameter of the electrospun nanofibers used was 239 nm, ranging from 113 to 398 nm. Experimental results indicated that the nanofibers showed good permeability (10 m) and high-efficiency filtration for aerosol nanoparticles (about 100 %), which can include black carbon (BC) and the new coronavirus. The pressure drop was 1.8 kPa at 1.6 cm s, which is similar to reported for some high-efficiency nanofiber filters. In addition, it also retains BC particles present in air, which was about 90 % for 375 nm and about 60 % for the 880 nm wavelength. Finally, this research provided information for future designs of indoor air filters and filter media for facial masks with renewable, non-toxic biodegradable, and potential antibacterial characteristics.

摘要

工业化进程的加快导致了大气污染物排放量的增加。与此同时,对气溶胶过滤技术进步的需求正朝着更可持续的技术发展。静电纺丝技术正日益受到关注,因为它能够生产含有不同添加剂的聚合物纳米纤维,还能获得小孔径和纤维直径;这些都是空气过滤材料所需的特性。因此,本工作旨在评估通过静电纺丝技术制备的醋酸纤维素(CA)纳米纤维和阳离子表面活性剂十六烷基溴化吡啶(CPB)对气溶胶纳米颗粒的截留过滤性能。使用扫描迁移率粒径分析仪(SMPS)对氯化钠(NaCl)气溶胶颗粒(直径7至300纳米)进行压降和收集效率测量。所用静电纺纳米纤维的平均直径为239纳米,范围在113至398纳米之间。实验结果表明,纳米纤维具有良好的透气性(10米),对气溶胶纳米颗粒具有高效过滤性能(约100%),其中包括黑碳(BC)和新型冠状病毒。在1.6厘米/秒的流速下,压降为1.8千帕,这与一些高效纳米纤维过滤器的报道相似。此外,它还能截留空气中的BC颗粒,对于375纳米的颗粒截留率约为90%,对于880纳米波长的颗粒截留率约为60%。最后,本研究为未来具有可再生、无毒可生物降解以及潜在抗菌特性的室内空气过滤器和口罩过滤介质的设计提供了信息。

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