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电有机合成——一项21世纪的技术。

Electro-organic synthesis - a 21 century technique.

作者信息

Pollok Dennis, Waldvogel Siegfried R

机构信息

Department of Chemistry, Johannes Gutenberg University Mainz Duesbergweg 10-14 55128 Mainz Germany

出版信息

Chem Sci. 2020 May 20;11(46):12386-12400. doi: 10.1039/d0sc01848a.

Abstract

The severe limitations of fossil fuels and finite resources influence the scientific community to reconsider chemical synthesis and establish sustainable techniques. Several promising methods have emerged, and electro-organic conversion has attracted particular attention from international academia and industry as an environmentally benign and cost-effective technique. The easy application, precise control, and safe conversion of substrates with intermediates only accessible by this method reveal novel pathways in synthetic organic chemistry. The popularity of electricity as a reagent is accompanied by the feasible conversion of bio-based feedstocks to limit the carbon footprint. Several milestones have been achieved in electro-organic conversion at rapid frequency, which have opened up various perspectives for forthcoming processes.

摘要

化石燃料的严重局限性和有限资源促使科学界重新考虑化学合成并建立可持续技术。一些有前景的方法已经出现,而有机电合成作为一种环境友好且具有成本效益的技术,尤其受到国际学术界和工业界的关注。这种方法易于应用、控制精确,并且能够安全地将底物转化为只有通过该方法才能获得的中间体,揭示了有机合成化学中的新途径。电作为一种试剂的广泛应用伴随着生物基原料的可行转化,以限制碳足迹。有机电合成在快速发展过程中已经取得了几个里程碑式的成果,为未来的工艺开辟了各种前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd9f/8162804/44b4e595322c/d0sc01848a-f1.jpg

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