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壳聚糖与活性炭复合膜对中性红染料的吸附作用

Adsorption of neutral red dye by chitosan and activated carbon composite films.

作者信息

de Freitas Fabiana Paiva, Carvalho Ana Márcia Macedo Ladeira, Carneiro Angélica de Cássia Oliveira, de Magalhães Mateus Alves, Xisto Mariana Fonseca, Canal Wagner Davel

机构信息

Universidade Federal de Viçosa, Brazil.

出版信息

Heliyon. 2021 Jul 22;7(7):e07629. doi: 10.1016/j.heliyon.2021.e07629. eCollection 2021 Jul.

Abstract

Research indicates the use of adsorbent materials to remove pollutants from wastewater and effluents, which can be obtained from renewable materials such as biomass, biopolymers (chitosan) or composites. Thus, the objective of this work was to produce and evaluate activated carbon (AC) and chitosan composite films as adsorbents of neutral red dye. AC films were produced using CO and water vapor. The variables of the activation process were time (1 and 2 h) and temperature (600 and 750 °C). Five films were produced, with one pure chitosan (T1) film and four activated carbon with chitosan films (T2, T3, T4 and T5). The T2 film refers to activated carbon produced at 600 °C for 1 h + chitosan, T3 to activated carbon produced at 600 °C for 2 h + chitosan, T4 to activated carbon produced at 750 °C for 1 h + chitosan and T5 to activated carbon produced at 750 °C for 2 h + chitosan. The T5 film increased its adsorption capacity by approximately 87% and its removal efficiency of neutral red dye by 43% compared to T1. The presence of activated carbon in the films provided an increase in the adsorption capacity of the neutral red dye.

摘要

研究表明,可使用吸附材料从废水和污水中去除污染物,这些吸附材料可从生物质、生物聚合物(壳聚糖)或复合材料等可再生材料中获得。因此,本研究的目的是制备并评估活性炭(AC)和壳聚糖复合膜作为中性红染料的吸附剂。采用CO和水蒸气制备AC膜。活化过程的变量为时间(1小时和2小时)和温度(600℃和750℃)。制备了五张膜,一张纯壳聚糖(T1)膜和四张活性炭与壳聚糖复合膜(T2、T3、T4和T5)。T2膜指在600℃下活化1小时的活性炭+壳聚糖,T3指在600℃下活化2小时的活性炭+壳聚糖,T4指在750℃下活化1小时的活性炭+壳聚糖,T5指在750℃下活化2小时的活性炭+壳聚糖。与T1相比,T5膜的吸附容量提高了约87%,中性红染料的去除效率提高了43%。膜中活性炭的存在提高了中性红染料的吸附容量。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab9e/8334384/a5e537bb7707/gr1.jpg

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