Division 4.2 - Materials and Air Pollutants, Federal Institute for Materials Research and Testing (BAM), Berlin, Germany.
Indoor Air. 2022 Mar;32(3):e13010. doi: 10.1111/ina.13010.
The diversity of fused filament fabrication (FFF) filaments continues to grow rapidly as the popularity of FFF-3D desktop printers for the use as home fabrication devices has been greatly increased in the past decade. Potential harmful emissions and associated health risks when operating indoors have induced many emission studies. However, the lack of standardization of measurements impeded an objectifiable comparison of research findings. Therefore, we designed a chamber-based standard method, i.e., the strand printing method (SPM), which provides a standardized printing procedure and quantifies systematically the particle emission released from individual FFF-3D filaments under controlled conditions. Forty-four marketable filament products were tested. The total number of emitted particles (TP) varied by approximately four orders of magnitude (10 ≤ TP ≤ 10 ), indicating that origin of polymers, manufacturer-specific additives, and undeclared impurities have a strong influence. Our results suggest that TP characterizes an individual filament product and particle emissions cannot be categorized by the polymer type (e.g., PLA or ABS) alone. The user's choice of a filament product is therefore decisive for the exposure to released particles during operation. Thus, choosing a filament product awarded for low emissions seems to be an easily achievable preemptive measure to prevent health hazards.
熔融沉积制造(FFF)线材的多样性随着 FFF-3D 桌面打印机作为家庭制造设备的普及而迅速增长,在过去十年中,这种打印机的使用大大增加。在室内操作时,可能会有害排放物并带来相关健康风险,这促使许多排放研究的开展。然而,由于测量缺乏标准化,阻碍了对研究结果的客观比较。因此,我们设计了一种基于腔室的标准方法,即丝束打印方法(SPM),该方法提供了标准化的打印程序,并在受控条件下系统地量化了从各个 FFF-3D 线材释放的颗粒排放。我们对 44 种市售线材产品进行了测试。释放颗粒的总数(TP)变化幅度约为四个数量级(10 ≤ TP ≤ 10 ),这表明聚合物的来源、制造商特定的添加剂和未申报的杂质有很大的影响。我们的结果表明,TP 可以表征单个线材产品,并且不能仅根据聚合物类型(例如 PLA 或 ABS)对颗粒排放进行分类。因此,用户对线材产品的选择对于在操作过程中释放颗粒的暴露至关重要。因此,选择一种获得低排放认可的线材产品似乎是一种简单可行的预防措施,可以防止健康危害。