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一种磁性多孔有机聚合物:在合成含吲哚、三唑和磺酰胺部分的杂化吡啶中的催化应用。

A magnetic porous organic polymer: catalytic application in the synthesis of hybrid pyridines with indole, triazole and sulfonamide moieties.

作者信息

Torabi Morteza, Yarie Meysam, Zolfigol Mohammad Ali, Azizian Saeid, Gu Yanlong

机构信息

Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University Hamedan Iran

Department of Physical Chemistry, Faculty of Chemistry, Bu-Ali Sina University Hamedan Iran.

出版信息

RSC Adv. 2022 Mar 21;12(14):8804-8814. doi: 10.1039/d2ra00451h. eCollection 2022 Mar 15.

Abstract

Herein, the synthesis and characterization of a triazine-based magnetic ionic porous organic polymer are reported. The structure, morphology, and components of the prepared structure have been investigated with several spectroscopic and microscopic techniques such as FT-IR, EDX, elemental mapping, TGA/DTA, SEM, TEM, VSM, and BET analysis. Also, catalytic application of the prepared triazine-based magnetic ionic porous organic polymer was investigated for the synthesis of hybrid pyridine derivatives bearing indole, triazole and sulfonamide groups. Furthermore, the prepared hybrid pyridine systems were characterized by FT-IR, H NMR, C NMR and mass analysis. A cooperative vinylogous anomeric-based oxidation pathway was suggested for the synthesis of target molecules.

摘要

本文报道了一种基于三嗪的磁性离子多孔有机聚合物的合成与表征。采用了多种光谱和显微镜技术,如傅里叶变换红外光谱(FT-IR)、能量散射X射线光谱(EDX)、元素映射、热重分析/差示热分析(TGA/DTA)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、振动样品磁强计(VSM)和比表面积分析(BET),对所制备结构的结构、形态和成分进行了研究。此外,还研究了所制备的基于三嗪的磁性离子多孔有机聚合物在合成含吲哚、三唑和磺酰胺基团的杂化吡啶衍生物中的催化应用。此外,通过傅里叶变换红外光谱(FT-IR)、氢核磁共振(¹H NMR)、碳核磁共振(¹³C NMR)和质谱分析对所制备的杂化吡啶体系进行了表征。提出了一种基于协同烯醇型异头物的氧化途径用于目标分子的合成。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b56/8984949/2c997720aab9/d2ra00451h-s1.jpg

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