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一种用于可视化和可穿戴检测河虾及水样中汞(II)的灵敏比率型荧光化学传感器。

A sensitive ratiometric fluorescent chemosensor for visual and wearable mercury (II) recognition in river prawn and water samples.

作者信息

Qi Meirong, Zhang Zihao, Li Lu, Mu Xiaoyue, Wang Yue

机构信息

College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China.

College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China.

出版信息

Food Chem. 2023 May 15;408:135211. doi: 10.1016/j.foodchem.2022.135211. Epub 2022 Dec 13.

Abstract

A novel ratiometric fluorescent probe p-RPT was prepared with triphenylamine and a rhodamine derivative. The probe displays high sensitivity and selectivity for Hg, which was applied in real water sample detection and biologic cell imaging. Hydrogel-coated paper sensors were fabricated with p-RPT, which displayed fluorescent colour change upon Hg ion contact with a detection limit of 1.2 × 10 M (∼10 ppb). In addition, flexible fluorescent p-RPT gloves were developed for visible and wearable Hg detection and applied to detect mercury (II) in river prawn samples. In summary, the p-RPT probe not only shows great potential in mercury (II) detection for food and water, but also provides a new perspective for wearable sensing apparatus.

摘要

一种新型的比率荧光探针p-RPT由三苯胺和罗丹明衍生物制备而成。该探针对汞具有高灵敏度和选择性,应用于实际水样检测和生物细胞成像。用p-RPT制备了水凝胶涂层纸质传感器,当汞离子接触时,该传感器会发生荧光颜色变化,检测限为1.2×10⁻⁷ M(约10 ppb)。此外,还开发了用于可见和可穿戴汞检测的柔性荧光p-RPT手套,并应用于检测河虾样品中的汞(II)。总之,p-RPT探针不仅在食品和水的汞(II)检测中显示出巨大潜力,而且为可穿戴传感装置提供了新的视角。

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