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超声辅助合成查尔酮:一种用于检测水介质中Fe的高灵敏度和选择性荧光化学传感器。

Ultrasound-Assisted Synthesis of Chalcone: A Highly Sensitive and Selective Fluorescent Chemosensor for the Detection of Fe in Aqueous Media.

作者信息

Khan Salman A, Alam Md Zafer, Mohasin Md, Ahmad Suhail, Salma Umme, Parveen Humaira, Mukhtar Sayeed, Al-Anazi Menier, Alotaibi Fatimah A, Abdelaziz Mahmoud A

机构信息

Physical Sciences (Chemistry), School of Sciences, Maulana Azad National Urdu University, Hyderabad, Telangana, 500032, India.

Department of Chemistry, Faculty of Science, University of Tabuk, Tabuk, 71491, Kingdom of Saudi Arabia.

出版信息

J Fluoresc. 2024 Mar;34(2):723-728. doi: 10.1007/s10895-023-03317-w. Epub 2023 Jun 24.

Abstract

The chalcone compound DHPO was synthesized through a chemical reaction between 1-(2-hydroxyphenyl)-ethanone and 3,4-dimethoxy benzaldehyde under ultrasound irradiation. The interaction between the DHPO compound and several metal ions was studied using fluorescence behavior, revealing that the chalcone function as a "turn on and turn off" switch fluorescent sensor, for selectively and sensitively detecting Fe ions. The process of fluorescence quenching and complexation of DHPO with Fe ion was further studied using methods such as Benesi-Hildebrand, Stern-Volmer plot, and job plot.

摘要

查尔酮化合物DHPO是通过1-(2-羟基苯基)-乙酮与3,4-二甲氧基苯甲醛在超声辐射下发生化学反应合成的。利用荧光行为研究了DHPO化合物与几种金属离子之间的相互作用,结果表明该查尔酮可作为一种“开启和关闭”开关型荧光传感器,用于选择性和灵敏地检测铁离子。采用Benesi-Hildebrand法、Stern-Volmer图和Job图等方法进一步研究了DHPO与铁离子的荧光猝灭和络合过程。

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