School of Chemical & Environmental Engineering, China University of Mining & Technology (Beijing), Beijing, 100083, China.
Beijing Institute of Mineral Geology, Beijing, 101500, China.
J Environ Manage. 2024 Feb;351:119838. doi: 10.1016/j.jenvman.2023.119838. Epub 2023 Dec 24.
Heavy metal contamination of soil commonly accompanies problems around gold mine tailings ponds. Fully investigating the distribution characteristics of heavy metals and the survival strategies of dominant plants in contaminated soils is crucial for effective pollution management and remediation. This study aims to investigate the contamination characteristics, sources of heavy metals (As, Cd, Pb, Hg, Cu, Zn, Cr, and Ni) in soils around gold mine tailings ponds areas (JHH and WZ) and to clarify the form distribution of heavy metals (As, Cd, Pb, Hg) in contaminated plots as well as their accumulation and translocation in native dominant plants. The results of the study showed that the concentrations of As, Pb, Cd, Cu, and Zn in soil exceeded the national limits at parts of the sampling sites in both study areas. The Nemerow pollution index showed that both study areas reached extreme high pollution levels. Spatial analysis showed that the main areas of contamination were concentrated around metallurgical plants and tailings ponds, with Cd exhibiting the most extensive area of contamination. In the JHH, As (74%), Cd (66%), Pb (77%), Zn (47%) were mainly from tailings releases, and Cu (52%) and Hg (51%) were mainly from gold ore smelting. In the WZ, As (42%), Cd (41%), Pb (73%), Cu (47%), and Zn (41%) were mainly from tailings releases. As, Cd, Pb, and Hg were mostly present in the residue state, and the proportion of water-soluble, ion-exchangeable, and carbonate-bound forms of Cd (19.93%) was significantly higher than that of other heavy metals. Artemisia L. and Amaranthus L. are the primary dominating plants, which exhibited superior accumulation of Cd compared to As, Pb, and Hg, and Artemisia L. demonstrated a robust translocation capacity for As, Pb, and Hg. Compared to the concentrations of other forms of soil heavy metals, the heavy metal content in Artemisia L correlates significantly better with the total soil heavy metal concentration. These results offer additional systematic data support and a deeper theoretical foundation to bolster pollution-control and ecological remediation efforts in mining areas.
土壤重金属污染通常伴随着金矿尾矿池周围的问题。全面调查重金属在污染土壤中的分布特征和优势植物的生存策略,对于有效进行污染管理和修复至关重要。本研究旨在调查金矿尾矿池地区(JHH 和 WZ)周围土壤的重金属(As、Cd、Pb、Hg、Cu、Zn、Cr 和 Ni)污染特征和来源,并阐明污染区重金属(As、Cd、Pb、Hg)的形态分布及其在本地优势植物中的积累和迁移。研究结果表明,两个研究区部分采样点土壤中 As、Pb、Cd、Cu 和 Zn 浓度超过国家限制。Nemerow 污染指数表明两个研究区均达到了极高污染水平。空间分析表明,主要污染区集中在冶金厂和尾矿池周围,Cd 的污染面积最广。在 JHH,As(74%)、Cd(66%)、Pb(77%)、Zn(47%)主要来自尾矿释放,Cu(52%)和 Hg(51%)主要来自金矿冶炼。在 WZ,As(42%)、Cd(41%)、Pb(73%)、Cu(47%)和 Zn(41%)主要来自尾矿释放。As、Cd、Pb 和 Hg 主要以残渣态存在,Cd 的水溶态、离子交换态和碳酸盐结合态比例(19.93%)明显高于其他重金属。蒿属(Artemisia L.)和苋属(Amaranthus L.)是主要的优势植物,它们对 Cd 的积累明显高于 As、Pb 和 Hg,而蒿属对 As、Pb 和 Hg 具有较强的迁移能力。与其他土壤重金属形态的浓度相比,Artemisia L. 中的重金属含量与土壤重金属总浓度的相关性更好。这些结果为矿区污染控制和生态修复提供了更多的系统数据支持和更深入的理论基础。