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揭开环境中邻苯二甲酸盐的神秘面纱

Unpacking Phthalates from Obscurity in the Environment.

作者信息

Baneshi Marzieh, Tonney-Gagne Jamey, Halilu Fatima, Pilavangan Kavya, Sabu Abraham Ben, Prosser Ava, Kanchanadevi Marimuthu Nikaran, Kaliaperumal Rajendran, Britten Allen J, Mkandawire Martin

机构信息

Department of Chemistry, School of Science and Technology, Cape Breton University, 1250 Grand Lake Road, Sydney, NS B1P 6L2, Canada.

Engineering Co-op Intern, Dalhousie University, 1334 Barrington Street, P.O. Box 15000, Halifax, NS B3H 4R2, Canada.

出版信息

Molecules. 2023 Dec 23;29(1):106. doi: 10.3390/molecules29010106.

Abstract

Phthalates (PAEs) are a group of synthetic esters of phthalic acid compounds mostly used as plasticizers in plastic materials but are widely applied in most industries and products. As plasticizers in plastic materials, they are not chemically bound to the polymeric matrix and easily leach out. Logically, PAEs should be prevalent in the environment, but their prevalence, transport, fate, and effects have been largely unknown until recently. This has been attributed, inter alia, to a lack of standardized analytical procedures for identifying them in complex matrices. Nevertheless, current advancements in analytical techniques facilitate the understanding of PAEs in the environment. It is now known that they can potentially impact ecological and human health adversely, leading to their categorization as endocrine-disrupting chemicals, carcinogenic, and liver- and kidney-failure-causing agents, which has landed them among contaminants of emerging concern (CECs). Thus, this review article reports and discusses the developments and advancements in PAEs' standard analytical methods, facilitating their emergence from obscurity. It further explores the opportunities, challenges, and limits of their advancements.

摘要

邻苯二甲酸酯(PAEs)是一组邻苯二甲酸化合物的合成酯,主要用作塑料材料中的增塑剂,但在大多数行业和产品中都有广泛应用。作为塑料材料中的增塑剂,它们与聚合物基体没有化学键合,容易渗出。从逻辑上讲,PAEs在环境中应该很普遍,但直到最近,它们的普遍程度、迁移、归宿和影响在很大程度上还不为人所知。这尤其归因于缺乏在复杂基质中识别它们的标准化分析程序。然而,分析技术的当前进展有助于了解环境中的PAEs。现在已知它们可能对生态和人类健康产生不利影响,导致它们被归类为内分泌干扰化学物质、致癌物质以及导致肝肾功能衰竭的物质,这使它们成为新出现的关注污染物(CECs)之一。因此,这篇综述文章报告并讨论了PAEs标准分析方法的发展和进步,促进它们从默默无闻中崭露头角。文章还进一步探讨了其进步带来的机遇、挑战和局限性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e2b/10780137/afb9aa56b256/molecules-29-00106-g001.jpg

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