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卤化铯铅钙钛矿及其复合材料的传感应用:全面综述

Sensing Utilities of Cesium Lead Halide Perovskites and Composites: A Comprehensive Review.

作者信息

Shellaiah Muthaiah, Sun Kien Wen, Thirumalaivasan Natesan, Bhushan Mayank, Murugan Arumugam

机构信息

Department of Research and Analytics, Saveetha Dental College and Hospitals, Saveetha Institute of Medical and Technical Sciences (SIMATS), Saveetha University, Chennai 600077, India.

Department of Applied Chemistry, National Yang-Ming Chiao Tung University, Hsinchu 300, Taiwan.

出版信息

Sensors (Basel). 2024 Apr 13;24(8):2504. doi: 10.3390/s24082504.

Abstract

Recently, the utilization of metal halide perovskites in sensing and their application in environmental studies have reached a new height. Among the different metal halide perovskites, cesium lead halide perovskites (CsPbX; X = Cl, Br, and I) and composites have attracted great interest in sensing applications owing to their exceptional optoelectronic properties. Most CsPbX nanostructures and composites possess great structural stability, luminescence, and electrical properties for developing distinct optical and photonic devices. When exposed to light, heat, and water, CsPbX and composites can display stable sensing utilities. Many CsPbX and composites have been reported as probes in the detection of diverse analytes, such as metal ions, anions, important chemical species, humidity, temperature, radiation photodetection, and so forth. So far, the sensing studies of metal halide perovskites covering all metallic and organic-inorganic perovskites have already been reviewed in many studies. Nevertheless, a detailed review of the sensing utilities of CsPbX and composites could be helpful for researchers who are looking for innovative designs using these nanomaterials. Herein, we deliver a thorough review of the sensing utilities of CsPbX and composites, in the quantitation of metal ions, anions, chemicals, explosives, bioanalytes, pesticides, fungicides, cellular imaging, volatile organic compounds (VOCs), toxic gases, humidity, temperature, radiation, and photodetection. Furthermore, this review also covers the synthetic pathways, design requirements, advantages, limitations, and future directions for this material.

摘要

最近,金属卤化物钙钛矿在传感领域的应用及其在环境研究中的应用达到了一个新高度。在不同的金属卤化物钙钛矿中,卤化铯铅钙钛矿(CsPbX;X = Cl、Br和I)及其复合材料因其优异的光电性能而在传感应用中引起了极大关注。大多数CsPbX纳米结构和复合材料具有良好的结构稳定性、发光性和电学性能,可用于开发独特的光学和光子器件。当暴露于光、热和水时,CsPbX及其复合材料可表现出稳定的传感效用。许多CsPbX及其复合材料已被报道可作为检测多种分析物的探针,如金属离子、阴离子、重要化学物质、湿度、温度、辐射光探测等。到目前为止,许多研究已经对涵盖所有金属和有机-无机钙钛矿的金属卤化物钙钛矿的传感研究进行了综述。然而,对CsPbX及其复合材料的传感效用进行详细综述可能会对那些寻求使用这些纳米材料进行创新设计的研究人员有所帮助。在此,我们对CsPbX及其复合材料在金属离子、阴离子、化学物质、爆炸物、生物分析物、农药、杀菌剂、细胞成像、挥发性有机化合物(VOCs)、有毒气体、湿度、温度、辐射和光探测定量方面的传感效用进行了全面综述。此外,本综述还涵盖了该材料的合成途径、设计要求、优点、局限性和未来发展方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8054/11054776/0cbf093e3e69/sensors-24-02504-g001.jpg

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