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利用聚酰胺基体从纺织废料中开发具有生态效率的复合材料。

Development of Eco-Efficient Composite from Textile Waste with Polyamide Matrix.

作者信息

Burgada Francisco, Arrieta Marina P, Borrell Begoña, Fenollar Octavio

机构信息

Textile Research Institute (AITEX), Carretera de Banyeres, 10, 03802 Alcoy, Spain.

Grupo de Investigación Polímeros, Caracterización y Aplicaciones (POLCA), 28006 Madrid, Spain.

出版信息

Polymers (Basel). 2024 Jul 19;16(14):2061. doi: 10.3390/polym16142061.

Abstract

The main aim of the present work is to evaluate and characterize the mechanical, morphological and thermal properties of wastes coming from the textile industry, mainly composed of cotton and polyester. These wastes will be thereafter implemented in commodity plastic such as polyamide, in order to develop new formulations of environmentally friendly materials. The composites were produced by extrusion and injection-molded processes in amounts between 15 wt.% and 60 wt.% of textile waste. With the objective of improving the properties of the materials, silanes were used as a compatibilizer between the textile fibers and the polymeric matrix. The effect of the compatibilizer in the composites was studied together with the effect of the amount of textile fiber added to the composites. Mechanical, thermal, morphological and wettability properties were analyzed for each composite. The results show that the use of silanes improves the interaction especially in those composites with a higher amount of textile waste, offering a balanced mechanical behavior with significantly high quantities. On the other hand, the melting temperature does not vary significantly with the introduction of silanes and textile waste content, although the incorporation of textile waste slightly reduces up to 23% the degradation temperature of the resulting composites. The wettability of the composites is also increased up to 16% with the incorporation of textile waste. Finally, the appearance of the composites with textile waste is strongly influenced by the incorporation of the reinforcement, offering shades close to dark brown in the whole range of compositions.

摘要

本工作的主要目的是评估和表征来自纺织工业的废料的机械、形态和热性能,这些废料主要由棉花和聚酯组成。此后,这些废料将被应用于聚酰胺等商品塑料中,以开发新型环保材料配方。通过挤出和注塑工艺制备复合材料,纺织废料的含量在15 wt.%至60 wt.%之间。为了改善材料性能,使用硅烷作为纺织纤维与聚合物基体之间的增容剂。研究了增容剂对复合材料的影响以及添加到复合材料中的纺织纤维量的影响。对每种复合材料的机械、热、形态和润湿性进行了分析。结果表明,硅烷的使用改善了相互作用,特别是在那些含有较高量纺织废料的复合材料中,提供了具有显著高数量的平衡机械性能。另一方面,尽管加入纺织废料会使所得复合材料的降解温度略有降低,最高可达23%,但引入硅烷和纺织废料含量后,熔点变化并不显著。加入纺织废料后,复合材料的润湿性也提高了16%。最后,含有纺织废料的复合材料的外观受到增强材料加入的强烈影响,在整个组成范围内呈现接近深棕色的色调。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b9a/11280886/e31acea7a51e/polymers-16-02061-g001.jpg

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