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中国红缨子高粱生产基地中微塑料的分布、特征及生态风险。

Distribution, characteristics, and ecological risks of microplastics in the Hongyingzi sorghum production base in China.

机构信息

Department of Brewing Engineering, Moutai Institute, Renhuai, GuiZhou, 564500, China.

Department of Brewing Engineering, Moutai Institute, Renhuai, GuiZhou, 564500, China.

出版信息

Environ Pollut. 2024 Nov 15;361:124866. doi: 10.1016/j.envpol.2024.124866. Epub 2024 Sep 1.

Abstract

Microplastics (MPs), an emerging pollutant of global concern, have been studied in the Hongyingzi sorghum production base. In this study, we investigated MPs in the surface soil (0-10 cm) and deeper soil (10-20 cm) in the Hongyingzi sorghum production base. Pollution characterization and ecological risk evaluation were conducted. The results revealed that the MP abundance ranged from 1.31 × 10 to 4.27 × 10 particles/kg, with an average of 1.42 ± 1.22 × 10 particles/kg. There was no clear correlation between the MP abundance and soil depth, and the ordinary kriging method predicted a range of 1.26 × 10-1.28 × 10 particles/kg in most of the study area, indicating a relatively uniform distribution. Among the 12 types of MPs detected, acrylates copolymer (ACR), polypropylene (PP), polyurethane (PU), and polymethyl methacrylate (PMMA) were the most frequently detected. These MPs primarily originated from packaging and advertising materials made from polyurethane and polyester used by Sauce Wine enterprises, as well as plastic products made from polyolefin used in daily life and agricultural activities. The particle size of MPs was primarily 20-100 μm. Overall, the proportion of the 20-100 μm MP was 95.1% in the surface soil layer and 86.7% in the deeper soil layer. Based on the pollution load index, the MP pollution level in the study area was classified as class I. Polymer hazard index evaluation revealed that the risk levels at all of the sampling sites ranged from IV to V, and ACR, PU, and PMMA were identified as significant sources of polymer hazard. Potential ecological index evaluation revealed that most of the soil samples collected from the study area were dangerous or extremely dangerous, and the surface soil posed a greater ecological risk than the deeper soil. These findings provide a scientific foundation for the prevention, control, and management of MP pollution in the Hongyingzi sorghum production base.

摘要

微塑料(MPs)作为一种新兴的全球性污染物,已经在红英子高粱生产基地得到了研究。在本研究中,我们调查了红英子高粱生产基地表层土壤(0-10cm)和深层土壤(10-20cm)中的 MPs。进行了污染特征和生态风险评估。结果表明,MP 丰度范围为 1.31×10 至 4.27×10 颗粒/kg,平均值为 1.42±1.22×10 颗粒/kg。MP 丰度与土壤深度之间没有明显的相关性,普通克里金方法预测研究区域大部分地区的范围为 1.26×10-1.28×10 颗粒/kg,表明分布相对均匀。在所检测到的 12 种 MPs 中,丙烯酸盐共聚物(ACR)、聚丙烯(PP)、聚氨酯(PU)和聚甲基丙烯酸甲酯(PMMA)是最常被检测到的。这些 MPs 主要来源于 Sauce Wine 企业使用的聚氨酯和聚酯包装和广告材料,以及日常生活和农业活动中使用的聚烯烃塑料产品。MPs 的粒径主要为 20-100μm。总体而言,表层土壤中 20-100μm 的 MPs 比例为 95.1%,深层土壤中为 86.7%。基于污染负荷指数,研究区的 MP 污染水平被归类为 I 级。聚合物危害指数评估表明,所有采样点的风险水平均在 IV 到 V 之间,ACR、PU 和 PMMA 被确定为聚合物危害的重要来源。潜在生态指数评估表明,研究区采集的大部分土壤样本都处于危险或极危险状态,表层土壤比深层土壤具有更大的生态风险。这些发现为红英子高粱生产基地的 MP 污染防治、控制和管理提供了科学依据。

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