对一氧化碳具有高选择性的异常空气稳定的铜（I）配合物。
Unusually air-stable copper(i) complexes showing high selectivity for carbon monoxide.
作者信息
Saeednia Borna, Sragow Aria M, Lin Yannan, Sheehan Colton J, Metlay Amy S, Gau Michael R, Dye Samantha A, O'Konski Sarah P, Mallouk Thomas E, Dmochowski Ivan J
机构信息
Department of Chemistry, University of Pennsylvania 231 S. 34th St. Philadelphia PA 19104 USA
出版信息
Chem Sci. 2025 Feb 19;16(12):5058-5063. doi: 10.1039/d5sc00237k. eCollection 2025 Mar 19.
Abstract
We report two Cu(i)-tren host molecules with unusual air-stability, as revealed by strong preference for axial CO binding over bent O. Spectroscopy, electrochemical, and X-ray crystal structure analyses indicate that the phenyl rotators of the capsule select for small axial ligands.
摘要
我们报道了两种具有异常空气稳定性的Cu(i)-tren主体分子，这通过对轴向CO结合而非弯曲的O的强烈偏好得以揭示。光谱、电化学和X射线晶体结构分析表明，胶囊的苯基旋转器选择了小的轴向配体。
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