Salma Umme, Alam Md Zafer, Ahmad Suhail, Mohasin Md, Khan Salman A
Department of Chemistry, School of Sciences, Maulana Azad National Urdu University, Hyderabad, 500032, Telangana, India.
J Fluoresc. 2025 Mar 21. doi: 10.1007/s10895-025-04202-4.
Triazole Schiff base as fluorescent chemosensor and fluorogenic cation sensor is crucial for the detection of metal ions. The diverse structures of triazole Schiff bases have raised concerns. Excellent luminous properties are produced by mixing donor and acceptor groups with delocalized π-orbitals due to the intramolecular charge transfer (ICT) mechanism. For Al metal ions, this work provides data on the triazole Schiff base, design, synthesis, and sensing mechanism (ON/OFF, OFF/ON, and ON-OFF-OFF) of these sensors, as well as their potential uses. We also examined how the sensor's photophysical characteristics alter when it coordinates with the metal ions, leading to modifications in its usual sensing behaviour, such as a shift from hypsochromic/bathochromic or hypochromic/hyperchromic. Researchers will use this review as a starting point to investigate triazole Schiff base-based sensors further.
三唑席夫碱作为荧光化学传感器和荧光阳离子传感器对于金属离子的检测至关重要。三唑席夫碱的多样结构引发了关注。由于分子内电荷转移(ICT)机制,通过将供体和受体基团与离域π轨道混合可产生优异的发光性能。对于铝金属离子,这项工作提供了有关三唑席夫碱的数据、这些传感器的设计、合成和传感机制(开/关、关/开和开-关-开)以及它们的潜在用途。我们还研究了传感器与金属离子配位时其光物理特性如何改变,从而导致其通常的传感行为发生变化,例如从紫移/红移或减色/增色转变。研究人员将以本综述为起点进一步研究基于三唑席夫碱的传感器。