Hrenović Jasna, Rajić Nevenka
Faculty of Science, Division of Microbiology, University of Zagreb, 1000 Zagreb, Croatia.
Faculty of Ecology and Environmental Protection, University Union Nikola Tesla, 11000 Belgrade, Serbia.
Materials (Basel). 2025 May 21;18(10):2411. doi: 10.3390/ma18102411.
Natural zeolites are highly effective adsorbents that can remove various metal cations which would otherwise contaminate the environment. However, different metal cations (Cu, Zn, and Ag) within their lattice or quaternary long-chain surfactant cations on their surface modify their affinity towards hazardous anions and promote antibacterial activity in natural zeolites. Specifically, natural zeolites in their non-modified form lack intrinsic antibacterial characteristics. NZ is the most widespread natural zeolite. This review presents the antibacterial efficiency of NZ containing transition metals, nano oxides, and organics. This effect is nonspecific and primarily driven by the nutritional makeup of the medium rather than the species of pathogenic bacteria under study. Studies on using NZ-based disinfectants to clean up contaminated water and soil and using modified and purified NZ to protect health are also considered. By eliminating toxic ions and, when modified by these toxic cations, removing pathogens from the environment, natural NZ can serve a dual function, providing it with the distinctive characteristics of a sustainable material.
天然沸石是高效吸附剂,能够去除各种可能污染环境的金属阳离子。然而,其晶格中的不同金属阳离子(铜、锌和银)或其表面的季铵盐长链表面活性剂阳离子会改变它们对有害阴离子的亲和力,并增强天然沸石的抗菌活性。具体而言,未改性的天然沸石缺乏内在抗菌特性。斜发沸石是分布最广的天然沸石。本文综述了含过渡金属、纳米氧化物和有机物的斜发沸石的抗菌效率。这种效应是非特异性的,主要由培养基的营养成分驱动,而非所研究的致病细菌种类。还考虑了关于使用基于斜发沸石的消毒剂清理受污染的水和土壤以及使用改性和纯化的斜发沸石来保护健康的研究。通过去除有毒离子,以及在被这些有毒阳离子改性时从环境中去除病原体,天然斜发沸石可以发挥双重作用,使其具有可持续材料的独特特性。