由N-杂环卡宾催化剂介导的仲醇的酯交换/酰化反应
Transesterification/Acylation of secondary alcohols mediated by N-heterocyclic carbene catalysts.
作者信息
Singh Rohit, Kissling Rebecca M, Letellier Marie-Anne, Nolan Steven P
机构信息
Department of Chemistry, University of New Orleans, New Orleans, Louisiana, USA.
出版信息
J Org Chem. 2004 Jan 9;69(1):209-12. doi: 10.1021/jo035431p.
PMID:14703402
Abstract
N-Heterocyclic carbenes (NHC) are efficient catalysts for transesterification/acylation reactions involving secondary alcohols. The catalytic transformations are carried out employing low catalyst loadings in convenient reaction times at room temperature.
摘要
N-杂环卡宾（NHC）是用于涉及仲醇的酯交换/酰化反应的高效催化剂。催化转化反应在室温下以低催化剂用量在适宜的反应时间内进行。
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