Alawi M A, Ammari N, al-Shuraiki Y
University of Jordan, Amman.
Arch Environ Contam Toxicol. 1992 Aug;23(2):235-9. doi: 10.1007/BF00212281.
Concentration of 15 organochlorine pesticides were determined by capillary gas chromatography in 59 human milk samples collected from the general population during 1989/1990 in the Jordanian capital of Amman. In addition to hexachlorbenzene (HCB), three groups of organochlorine compounds namely, DDT and its metabolites, hexachlorcyclohexane (HCH-isomers) and the cyclopentadiene group (aldrin, dieldrin, endrin, heptachlor, and heptachlor epoxide) were analyzed. The results show that almost all samples contained HCB, beta-HCH, p,p'-DDE and p,p'-DDT, whereas p,p'-DDD, heptachlor, alpha-HCH, gamma-HCH and o,p'DDT were found in 42, 40, 33, 22 and 20 analyzed samples, respectively. The concentration of HCB, beta-HCH, p,p'-DDE, p,p'-DDT and heptachlor expressed on a milk-fat basis (median in mg/kg milk fat): 0.29, 0.4, 2.04, and 0.7 respectively. For the comparative purposes and in order to try to find the possible sources of mother-milk contaminations, different types of locally produced and imported cow milk samples were also analyzed for the same organochlorine compounds. Almost all types of tested milk were contaminated with p,p'-DDE.
采用毛细管气相色谱法测定了1989/1990年期间从约旦首都安曼普通人群中采集的59份母乳样本中15种有机氯农药的含量。除六氯苯(HCB)外,还分析了三组有机氯化合物,即滴滴涕及其代谢物、六氯环己烷(HCH异构体)和环戊二烯类(艾氏剂、狄氏剂、异狄氏剂、七氯和环氧七氯)。结果表明,几乎所有样本都含有六氯苯、β-六氯环己烷、p,p'-滴滴伊和p,p'-滴滴涕,而在分别分析的42、40、33、22和20个样本中发现了p,p'-滴滴滴、七氯、α-六氯环己烷、γ-六氯环己烷和o,p'-滴滴涕。以乳脂计的六氯苯、β-六氯环己烷、p,p'-滴滴伊、p,p'-滴滴涕和七氯的浓度(乳脂中毫克/千克的中位数)分别为:0.29、0.4、2.04和0.7。为了进行比较并试图找出母乳污染的可能来源,还对不同类型的本地生产和进口牛奶样本进行了相同有机氯化合物的分析。几乎所有测试类型的牛奶都被p,p'-滴滴伊污染。