Kikuchi Masafumi, Takahashi Masatoshi, Okuno Osamu
Division of Dental Biomaterials, Graduate School of Dentistry, Tohoku University, 4-1 Seiryo-machi, Sendai, Miyagi 980-8575, Japan.
Dent Mater. 2006 Jul;22(7):641-6. doi: 10.1016/j.dental.2005.05.015. Epub 2005 Oct 10.
This study investigated the effect of alloying titanium with gold, silver, or copper on the elastic properties of the alloys.
A series of binary titanium alloys was made with four concentrations of gold, silver, or copper (5, 10, 20, and 30 mass%) in an argon-arc melting furnace. The Young's moduli and Poisson's ratios of the alloy castings were determined with an ultrasonic-pulse method. The density of each alloy was previously measured by the Archimedes' principle. Results were analyzed using one-way ANOVA and the Scheffé's test.
The densities of Ti-Au, Ti-Ag, and Ti-Cu alloys monotonically increased as the concentration of alloying elements increased. As the concentration of gold or silver increased to 20%, the Young's modulus significantly decreased, followed by a subsequent increase in value. As the concentration of copper increased, the Young's modulus monotonically increased. The Young's moduli of all the Ti-Cu alloys were significantly higher than that of the titanium.
The density of all the experimental alloys was virtually independent of the alloy phases, while the Young's moduli and Poisson's ratios of the alloys were dependent. The addition of gold or silver slightly reduced the Young's modulus of the titanium when the alloy phase was single alpha. The increase in the Young's modulus of the Ti-Cu alloys is probably due to the precipitation of intermetallic compound Ti2Cu. Copper turned out to be a moderate stiffener that gains a Young's modulus of titanium up to 20% at the copper concentration of 30 mass%.
本研究调查了钛与金、银或铜合金化对合金弹性性能的影响。
在氩弧熔炼炉中制备了一系列含有四种浓度(5%、10%、20%和30%质量分数)金、银或铜的二元钛合金。用超声脉冲法测定合金铸件的杨氏模量和泊松比。每种合金的密度预先用阿基米德原理测量。结果采用单因素方差分析和谢弗检验进行分析。
Ti-Au、Ti-Ag和Ti-Cu合金的密度随着合金元素浓度的增加而单调增加。当金或银的浓度增加到20%时,杨氏模量显著降低,随后又升高。随着铜浓度的增加,杨氏模量单调增加。所有Ti-Cu合金的杨氏模量均显著高于钛的杨氏模量。
所有实验合金的密度实际上与合金相无关,而合金的杨氏模量和泊松比则与合金相有关。当合金相为单一α相时,添加金或银会略微降低钛的杨氏模量。Ti-Cu合金杨氏模量的增加可能是由于金属间化合物Ti2Cu的析出。铜是一种适度的强化剂,在铜浓度为30%质量分数时,可使钛的杨氏模量提高20%。