钌催化的芳基硼酸与芳烃的有氧氧化偶联反应。

Ru-catalyzed aerobic oxidative coupling of arylboronic acids with arenes.

机构信息

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China.

出版信息

Chem Commun (Camb). 2011 Feb 7;47(5):1497-9. doi: 10.1039/c0cc04322b. Epub 2010 Nov 16.

DOI:10.1039/c0cc04322b

PMID:21082112

Abstract

A Ru-catalyzed oxidative coupling of arenes with boronic acids using molecular oxygen via direct C-H activation is reported. Both the scope and the mechanism of the process are discussed.

摘要

报道了一种 Ru 催化的芳基硼酸与分子氧的氧化偶联反应，通过直接 C-H 活化实现。讨论了该过程的范围和机理。