直接官能化第 10 族 N-杂环卡宾配合物以提高多样性。
Direct functionalisation of group 10 N-heterocyclic carbene complexes for diversity enhancement.
机构信息
Institute of Physics and Chemistry of Materials of Strasbourg (IPCMS), University of Strasbourg - CNRS UMR7504, 23 rue du Loess, 67034 Strasbourg, France.
出版信息
Chem Commun (Camb). 2011 May 28;47(20):5864-6. doi: 10.1039/c1cc11391g. Epub 2011 Apr 18.
PMID:21503314
Abstract
The synthesis of alkyne-substituted N-heterocyclic carbene complexes of Pd(II) and Pt(II) is reported. Catalyzed 1,3-dipolar cycloaddition with azides has been applied as a modular way of functionalisation of group 10 transition metal NHC complexes to generate potentially new metallodrugs.
摘要
报告了钯（II）和铂（II）的炔基取代 N-杂环卡宾配合物的合成。叠氮化物的催化 1,3-偶极环加成反应已被用作功能化第 10 族过渡金属 NHC 配合物的模块化方法，以生成潜在的新型金属药物。
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