叶状聚[[μ(2)-1,4-双-(环己基硫烷基甲基)苯-κS:S'](μ(2)-硝酸根-κO:O')银(I)]
Phyllo-poly[[μ(2)-1,4-bis-(cyclo-hexyl-sulfanylmeth-yl)benzene-κS:S'](μ(2)-nitrato-κO:O')silver(I)].
作者信息
Kim Tae Ho, Shin Yong Woon, Park Ki-Min, Kim Jineun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 11;65(Pt 4):m385. doi: 10.1107/S1600536809007910.
The title compound, Ag(NO(3))(C(20)H(30)S(2)), was synthesized by the reaction of silver nitrate and 1,4-bis-(cyclo-hexyl-thio-meth-yl)benzene (bctmb) in acetonitrile. The coordination polymer exhibits a two-dimensional layer structure. The layers are wave-like and parallel to the crystallographic ac plane; Ag(I) ions are linked by the bctmb ligands and nitrate anions along the crystallographic a and c directions, respectively. In addition, the crystal structure is stabilized by C-H⋯O hydrogen bonds.
标题化合物[Ag(NO₃)(C₂₀H₃₀S₂)]ₙ是通过硝酸银与1,4-双（环己基硫甲基）苯（bctmb）在乙腈中反应合成的。该配位聚合物呈现二维层状结构。这些层呈波浪状且平行于晶体学ac平面；Ag(I)离子分别通过bctmb配体和硝酸根阴离子沿晶体学a和c方向相连。此外，晶体结构通过C-H⋯O氢键得以稳定。
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