Applied Superconductivity Center, National High Magnetic Field Laboratory, Florida State University, 2031 East Paul Dirac Drive, Tallahassee, Florida 32310, USA.
European Organization for Nuclear Research, Geneva CH-1211, Switzerland.
Nat Mater. 2014 Apr;13(4):375-81. doi: 10.1038/nmat3887. Epub 2014 Mar 9.
Magnets are the principal market for superconductors, but making attractive conductors out of the high-temperature cuprate superconductors (HTSs) has proved difficult because of the presence of high-angle grain boundaries that are generally believed to lower the critical current density, J(c). To minimize such grain boundary obstacles, HTS conductors such as REBa2Cu3O(7-x) and (Bi, Pb)2Sr2Ca2Cu3O(10-x) are both made as tapes with a high aspect ratio and a large superconducting anisotropy. Here we report that Bi2Sr2CaCu2O(8-x) (Bi-2212) can be made in the much more desirable isotropic, round-wire, multifilament form that can be wound or cabled into arbitrary geometries and will be especially valuable for high-field NMR magnets beyond the present 1 GHz proton resonance limit of Nb3Sn technology. An appealing attribute of this Bi-2212 conductor is that, being without macroscopic texture, it contains many high-angle grain boundaries but nevertheless attains a very high J(c) of 2,500 A mm(-2) at 20 T and 4.2 K. The large potential of the conductor has been demonstrated by building a small coil that generated almost 2.6 T in a 31 T background field. This demonstration that grain boundary limits to high Jc can be practically overcome underlines the value of a renewed focus on grain boundary properties in non-ideal geometries.
磁铁是超导材料的主要市场,但由于存在高角度晶界,高温铜酸盐超导体(HTS)很难制成有吸引力的导体,一般认为这些晶界会降低临界电流密度 J(c)。为了最小化这种晶界障碍,像 REBa2Cu3O(7-x) 和 (Bi, Pb)2Sr2Ca2Cu3O(10-x) 这样的 HTS 导体都被制成具有高纵横比和大超导各向异性的带材。在这里,我们报告说 Bi2Sr2CaCu2O(8-x) (Bi-2212) 可以制成更理想的各向同性、圆形线材、多丝形式,可以缠绕或编织成任意形状,对于超出目前 Nb3Sn 技术的 1 GHz 质子共振限制的高场 NMR 磁铁将特别有价值。这种 Bi-2212 导体吸引人的一个属性是,由于没有宏观织构,它包含许多高角度晶界,但仍能在 20 T 和 4.2 K 下达到非常高的 J(c)为 2500 A mm(-2)。该导体的巨大潜力已经通过构建一个小线圈得到了证明,该线圈在 31 T 的背景磁场中产生了近 2.6 T 的磁场。这一证明表明,在非理想几何形状下,晶界对高 Jc 的限制实际上可以克服,这凸显了重新关注非理想晶界特性的价值。