Gomez Virginia, Levin Marcus, Saber Anne T, Irusta Silvia, Dal Maso Miikka, Hanoi Roberto, Santamaria Jesus, Jensen Keld A, Wallin Håkan, Koponen Ismo K
1.Department of Chemical Engineering, Nanoscience Institute of Aragon, Mariano Esquillor, I+D building, 50018 Zaragoza, Spain
2.National Research Centre for Working Environment, Lersø Park Allé 105, Copenhagen, Denmark 3.Department of Micro- and Nanotechnology, Technical University of Denmark, DK-2800 Lyngby, Denmark.
Ann Occup Hyg. 2014 Oct;58(8):983-94. doi: 10.1093/annhyg/meu046. Epub 2014 Jul 16.
The release of dust generated during sanding or sawing of nanocomposites was compared with conventional products without nanomaterials. Epoxy-based polymers with and without carbon nanotubes, and paints with different amounts of nano-sized titanium dioxide, were machined in a closed aerosol chamber. The temporal evolution of the aerosol concentration and size distribution were measured simultaneously. The morphology of collected dust by scanning electron microscopy was different depending on the type of nanocomposites: particles from carbon nanotubes (CNTs) nanocomposites had protrusions on their surfaces and aggregates and agglomerates are attached to the paint matrix in particles emitted from alkyd paints. We observed no significant differences in the particle size distributions when comparing sanding dust from nanofiller containing products with dust from conventional products. Neither did we observe release of free nanomaterials. Instead, the nanomaterials were enclosed or partly enclosed in the matrix. A source strength term Si (cm(-3) s(-1)) that describes particle emission rates from continuous sources was introduced. Comparison between the Si parameters derived from sanding different materials allows identification of potential effects of addition of engineered nanoparticles to a composite.
将纳米复合材料打磨或锯切过程中产生的粉尘释放情况与不含纳米材料的传统产品进行了比较。在封闭的气溶胶室中对含和不含碳纳米管的环氧基聚合物以及含有不同量纳米级二氧化钛的涂料进行加工。同时测量了气溶胶浓度和粒径分布的时间演变。通过扫描电子显微镜观察,收集到的粉尘形态因纳米复合材料类型而异:碳纳米管(CNT)纳米复合材料产生的颗粒表面有突起,而醇酸漆排放的颗粒中,聚集体和团聚体附着在涂料基体上。比较含纳米填料产品的打磨粉尘与传统产品的粉尘时,我们未观察到粒径分布有显著差异。我们也未观察到游离纳米材料的释放。相反,纳米材料被包裹在基体中或部分被包裹在基体中。引入了一个描述连续源颗粒排放速率的源强项Si(cm⁻³ s⁻¹)。通过比较打磨不同材料得出的Si参数,可以确定向复合材料中添加工程纳米颗粒的潜在影响。