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美藤果(南美油藤)油中甘油酯类和不皂化物的表征

Characterization of glyceridic and unsaponifiable compounds of Sacha inchi (Plukenetia huayllabambana L.) oils.

作者信息

Chasquibol Nancy A, del Aguila Chellah, Yácono Juan C, Guinda Ángeles, Moreda Wenceslao, Gómez-Coca Raquel B, Pérez-Camino M Carmen

机构信息

Faculty of Industrial Engineering, Institute of Scientific Research, (IDIC), Universidad de Lima , Avenida Javier Prado Este, cuadra 46 s/n, Monterrico, Lima 33, Perú

出版信息

J Agric Food Chem. 2014 Oct 15;62(41):10162-9. doi: 10.1021/jf5028697. Epub 2014 Oct 2.

Abstract

This work deals with the characterization of the main glyceridic and unsaponifiable components of oils obtained from Sacha inchi (Plukenetia huayllabambana L.) seed ecotypes collected during two harvests in the Department of Amazonas in Peru. The seed-oil yield was 30.3-41.2%; standing out are the high percentages of the ω3- and ω6-fatty acids series whose ranges lie within those of the present Regulation for Sacha inchi oils. Triacylglycerols with even equivalent carbon number (ECN; 36-42) were the main components. Minor glyceridic polar compounds such as oxidized triglycerides, diglycerides, monoglycerides, and free fatty acids were determined by high-performance size exclusion chromatography. The low campesterol/stigmasterol ratio (1:6), unusual in the majority of vegetable oils, stands out. Regarding aliphatic hydrocarbons, these oils showed a particular profile for the saturated series of odd and even carbon atom numbers. According to our results Sacha inchi P. huayllabambana oils can be offered as a good alternative to P. volubilis, the species mainly commercialized for this vegetable oil.

摘要

这项工作研究了从秘鲁亚马孙地区两次收获期间采集的印加果(Plukenetia huayllabambana L.)种子生态型中提取的油的主要甘油酯和不皂化物成分的特性。种子油产量为30.3 - 41.2%;值得注意的是,ω3和ω6脂肪酸系列的百分比很高,其范围在现行印加果油法规规定的范围内。具有偶数等效碳原子数(ECN;36 - 42)的三酰甘油是主要成分。通过高效尺寸排阻色谱法测定了少量甘油酯极性化合物,如氧化甘油三酯、甘油二酯甘油单酯和游离脂肪酸。低菜油甾醇/豆甾醇比率(1:6)在大多数植物油中并不常见,十分突出。关于脂肪烃,这些油在奇数和偶数碳原子数的饱和系列中呈现出特定的分布特征。根据我们的结果,印加果(Plukenetia huayllabambana)油可以作为主要商业化生产这种植物油的缠绕油麻藤(Plukenetia volubilis)的良好替代品。

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