Microelectronics Research Center, Department of Electrical and Computer Engineering, The University of Texas at Austin , Austin, Texas 78758, United States.
Nano Lett. 2015 Mar 11;15(3):1883-90. doi: 10.1021/nl5047329. Epub 2015 Mar 2.
High-mobility two-dimensional (2D) semiconductors are desirable for high-performance mechanically flexible nanoelectronics. In this work, we report the first flexible black phosphorus (BP) field-effect transistors (FETs) with electron and hole mobilities superior to what has been previously achieved with other more studied flexible layered semiconducting transistors such as MoS2 and WSe2. Encapsulated bottom-gated BP ambipolar FETs on flexible polyimide afforded maximum carrier mobility of about 310 cm(2)/V·s with field-effect current modulation exceeding 3 orders of magnitude. The device ambipolar functionality and high-mobility were employed to realize essential circuits of electronic systems for flexible technology including ambipolar digital inverter, frequency doubler, and analog amplifiers featuring voltage gain higher than other reported layered semiconductor flexible amplifiers. In addition, we demonstrate the first flexible BP amplitude-modulated (AM) demodulator, an active stage useful for radio receivers, based on a single ambipolar BP transistor, which results in audible signals when connected to a loudspeaker or earphone. Moreover, the BP transistors feature mechanical robustness up to 2% uniaxial tensile strain and up to 5000 bending cycles.
二维(2D)高迁移率半导体是高性能机械柔性纳米电子学的理想选择。在这项工作中,我们报告了首例具有电子和空穴迁移率的柔性黑磷(BP)场效应晶体管(FET),优于之前使用其他更具研究价值的柔性层状半导体晶体管(如 MoS2 和 WSe2)所达到的性能。在柔性聚酰亚胺上封装底栅 BP 双极 FET 可提供约 310 cm2/V·s 的最大载流子迁移率,场效应电流调制超过 3 个数量级。该器件的双极性功能和高迁移率可用于实现包括双极性数字逆变器、倍频器和模拟放大器在内的柔性技术的基本电子系统电路,其电压增益高于其他报道的层状半导体柔性放大器。此外,我们还展示了首个基于单个双极 BP 晶体管的柔性 BP 调幅(AM)解调器,这是一种用于无线电接收器的有源级,当连接到扬声器或耳机时,会产生可听见的信号。此外,BP 晶体管具有高达 2%的单轴拉伸应变和高达 5000 次弯曲循环的机械鲁棒性。