一种基于新型哌啶衍生席夫碱的“开启型”铜化学传感器。
A New Piperidine Derivatized-Schiff Base Based "Turn-on" CuChemo-Sensor.
作者信息
Uyanik Ibrahim, Oguz Mehmet, Bhatti Asif Ali, Uyanik Arzu, Yilmaz Mustafa
机构信息
Faculty of Technology, Department of Metallurgical and Materials Engineering, Selcuk University, 42075, Konya, Turkey.
Department of Chemistry, Selcuk University, 42031, Konya, Turkey.
出版信息
J Fluoresc. 2017 May;27(3):791-797. doi: 10.1007/s10895-016-2013-y. Epub 2016 Dec 28.
In this study, we report the synthesis of new Schiff base E-1-(((1-benzylpiperidin-4-yl)imino)methyl)naphthalenee-2-ol (L) and evaluation of its fluorescence response toward Cu ion. Preliminary, solvent effect, metal selectivity and metal ligand ratio were analyzed through UV-Visible study. Fluorescence response toward Cu was carried to assess the fluorescent property of synthesized Schiff base. The probe exhibited a higher fluorescence enhancement in the presence of Cu over other metal ions (Ni, Zn, Hg, Co, Cd, Al, Fe, and Pb). The binding stoichiometry between L and Cu has been investigated using Job's plot and Benesi-Hildebrand equation and it was found that ligand L can form 1:1 L-Cu complex with binding constant (K ) of 4 × 10 LM.
在本研究中，我们报道了新型席夫碱E-1-(((1-苄基哌啶-4-基)亚氨基)甲基)萘-2-醇(L)的合成及其对铜离子的荧光响应评估。通过紫外可见光谱研究初步分析了溶剂效应、金属选择性和金属配体比例。对铜进行荧光响应以评估合成席夫碱的荧光性质。该探针在铜存在下比其他金属离子（镍、锌、汞、钴、镉、铝、铁和铅）表现出更高的荧光增强。使用乔布曲线和贝内西-希尔德布兰德方程研究了L与铜之间的结合化学计量，发现配体L可以形成1:1的L-Cu配合物，结合常数(K)为4×10 LM。
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