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各种电化学技术在不同传感平台上用于重金属离子检测的综述。

A review on various electrochemical techniques for heavy metal ions detection with different sensing platforms.

机构信息

CSIR-Central Scientific Instruments Organisation, Chandigarh 160030, India.

IISER, Indian Institute of Science Education and Research, Mohali, Punjab 140306,India.

出版信息

Biosens Bioelectron. 2017 Aug 15;94:443-455. doi: 10.1016/j.bios.2017.03.031. Epub 2017 Mar 18.

Abstract

Heavy metal ions are non-biodegradable and contaminate most of the natural resources occurring in the environment including water. Some of the heavy metals including Lead (Pb), Mercury (Hg), Arsenic (As), Chromium (Cr) and Cadmium (Cd) are considered to be highly toxic and hazardous to human health even at trace levels. This leads to the requirement of fast, accurate and reliable techniques for the detection of heavy metal ions. This review presents various electrochemical detection techniques for heavy metal ions those are user friendly, low cost, provides on-site and real time monitoring as compared to other spectroscopic and optical techniques. The categorization of different electrochemical techniques is done on the basis of different types of detection signals generated due to presence of heavy metal ions in the solution matrix like current, potential, conductivity, electrochemical impedance, and electrochemiluminescence. Also, the recent trends in electrochemical detection of heavy metal ions with various types of sensing platforms including metals, metal films, metal oxides, nanomaterials, carbon nano tubes, polymers, microspheres and biomaterials have been evoked.

摘要

重金属离子是不可生物降解的,会污染环境中存在的大部分自然资源,包括水。一些重金属,如铅(Pb)、汞(Hg)、砷(As)、铬(Cr)和镉(Cd),即使在痕量水平下,也被认为对人类健康具有高度毒性和危害性。这就需要快速、准确、可靠的技术来检测重金属离子。本综述介绍了各种电化学检测技术,这些技术具有用户友好、低成本的特点,与其他光谱和光学技术相比,可以提供现场实时监测。不同电化学技术的分类是基于在溶液基质中存在重金属离子时产生的不同类型的检测信号,例如电流、电位、电导率、电化学阻抗和电化学发光。此外,还讨论了各种类型的传感平台,包括金属、金属薄膜、金属氧化物、纳米材料、碳纳米管、聚合物、微球和生物材料,用于电化学检测重金属离子的最新趋势。

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