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一种基于喹啉席夫碱的新型铁比色荧光传感器。

A novel colorimetric fluorescence sensor for Fe based on quinoline Schiff base.

作者信息

Li Bin, Tian Jianfei, Zhang Dan, Tian Fuli

机构信息

College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, P. R. China.

出版信息

Luminescence. 2017 Dec;32(8):1567-1573. doi: 10.1002/bio.3361. Epub 2017 Jul 7.

Abstract

A novel fluorescent sensor bearing a quinoline and an anisidine moiety has been developed for highly selective detection of Fe , which shows photo-induced electron transfer (PET) behavior induced by Fe . Binding of Fe to the sensor induced the electron of C = N group transfer from quinoline to iron, the result exhibits fluorescent enhancement. With the features of easy synthesis, simple structural skeleton and excellent sensing ability, the newly synthesized chemosensor also applied as a highly selective fluorescent probe in complex samples containing various competitive metal ions. The probe could fulfill various needs in biological and environmental fields.

摘要

一种带有喹啉和茴香胺部分的新型荧光传感器已被开发用于高选择性检测铁,该传感器显示出由铁诱导的光致电子转移(PET)行为。铁与传感器的结合诱导了碳氮双键的电子从喹啉转移到铁上,结果显示荧光增强。新合成的化学传感器具有合成简便、结构骨架简单和传感能力优异的特点,还可作为一种高选择性荧光探针应用于含有各种竞争性金属离子的复杂样品中。该探针可满足生物和环境领域的各种需求。

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