State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Textiles, Donghua University, Shanghai 201620, China.
Nanoscale. 2019 Jan 31;11(5):2289-2298. doi: 10.1039/c8nr09288e.
Low-density nanofibrous aerogels enable various applications but are often hindered by their fragile bendability and poor tensile strength. Herein, we report a strategy to design nanofibrous aerogels with robust bendability and superelastic property, which has been achieved by fabricating bamboo lashing-like structures through a freeze-drying method. The obtained reinforced nanofibrous aerogels (RNFAs) can maintain their structural integrity after 100 bending-recovery cycles at a bending angle of about 100°. Particularly, the RNFAs can completely revive from large deformation with a fast recovery speed (∼834 mm s-1). Significantly, the internal hierarchical porous structures and hydrophobicity of the materials provide them with ultralight properties (density <11 mg cm-3), efficient sound absorption capability (noise reduction coefficient of 0.41) and good moisture resistance; thus, they are promising options in cabins, vehicles, and the regulation of indoor reverberation.
低密度纳米纤维气凝胶具有多种应用,但通常因其脆弱的柔韧性和较差的拉伸强度而受到限制。在此,我们报告了一种通过冷冻干燥方法制造具有强柔韧性和超弹性的纳米纤维气凝胶的策略。所得到的增强型纳米纤维气凝胶(RNFAs)在约 100°的弯曲角度下经过 100 次弯曲-恢复循环后仍能保持其结构完整性。特别地,RNFAs 可以从大变形中完全恢复,恢复速度很快(约 834mm s-1)。显著地,材料的内部分级多孔结构和疏水性为其提供了超轻的特性(密度<11mg cm-3)、高效的吸声能力(降噪系数为 0.41)和良好的耐湿性;因此,它们在舱室、车辆和室内混响调节方面具有广阔的应用前景。