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基于还原氧化石墨烯的氧化镉纳米复合材料的绿色合成及其电学和抗菌性能。

Green synthesis of cadmium oxide decorated reduced graphene oxide nanocomposites and its electrical and antibacterial properties.

机构信息

Department of Polymer Science and Technology, University of Calcutta, 92 A.P.C. Road, Kolkata 700009, India; Department of Chemistry, Budge Budge Institute of Technology, Nischintapur, Budge Budge, Kolkata 700137, India.

Department of Polymer Science and Technology, University of Calcutta, 92 A.P.C. Road, Kolkata 700009, India.

出版信息

Mater Sci Eng C Mater Biol Appl. 2019 Jun;99:696-709. doi: 10.1016/j.msec.2019.01.128. Epub 2019 Feb 6.

Abstract

A green, efficient synthesis of cadmium oxide decorated reduced graphene oxide nanocomposites (RGO/CdO) was prepared by one-step co-precipitation and hydrothermal method. Crystalline nature of the nanocomposites was characterized by X-ray diffraction analysis. To evaluate the structural morphology and particle size, high resolution transmission electron microscopy were used. X-ray photoelectron spectroscopy, Raman spectroscopy and Fourier transform infrared spectroscopy techniques were employed to establish chemical structure of the nanocomposites and Atomic Force Microscopy was done to measure the thickness. The optical properties were evaluated by UV-visible absorption spectroscopy. Thermo-gravimetric analysis, BET surface area and zeta potential measurements were carried out to study the thermal and surface characteristics. The CdO nano-particles (NPs) decorated on RGO sheets exhibit better electrical conductivity compared to RGO. The antibacterial activity of the nanocomposites has also been monitored in different culture media imparting good potentiality than RGO.

摘要

通过一步共沉淀和水热法制备了绿色、高效的氧化镉修饰还原氧化石墨烯纳米复合材料(RGO/CdO)。通过 X 射线衍射分析对纳米复合材料的晶体性质进行了表征。为了评估结构形态和颗粒尺寸,使用了高分辨率透射电子显微镜。X 射线光电子能谱、拉曼光谱和傅里叶变换红外光谱技术用于确定纳米复合材料的化学结构,原子力显微镜用于测量厚度。通过紫外-可见吸收光谱评估光学性质。进行了热重分析、BET 表面积和 ζ 电位测量,以研究热和表面特性。与 RGO 相比,负载在 RGO 片上的 CdO 纳米颗粒(NPs)表现出更好的导电性。纳米复合材料在不同的培养基中也表现出了良好的抗菌活性,比 RGO 更有潜力。

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