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乌恰利湿地复合体(UWC)——拉姆萨尔湿地的沉积物和选择性植物中金属的生态风险评估。

Ecological risk assessment of metals in sediments and selective plants of Uchalli Wetland Complex (UWC)-a Ramsar site.

机构信息

Sustainable Development Study Centre, Government College University, Lahore, Pakistan.

Department of Mathematics and Statistics, The University of Lahore, Lahore, Pakistan.

出版信息

Environ Sci Pollut Res Int. 2019 Jul;26(19):19136-19152. doi: 10.1007/s11356-019-04711-3. Epub 2019 Apr 10.

Abstract

Wetlands act as kidneys of land and facilitate remediation of metals and other harmful pollutants through uptake by aquatic macrophytes. The aim of the present study was to investigate metal concentrations in sediments and plants, sources of metal origin, and contamination level in Uchalli Wetland Complex. Sediment samples were collected from 15 randomly selected sites. Metal concentrations (Cd, Pb, Ni, Cu, Zn, Cr, As, Mn) in sediments and macrophytes were determined during summer and winter seasons using the inductively coupled plasma technique. Metal concentrations in sediments during summer and winter seasons were in the order as follows: As > Mn > Zn > Cr > Ni > Cd > Pb > Cu and As > Mn > Zn > Cr > Ni > Pb > Cd >Cu respectively. All analyzed metals were within European Union (EU) limits. In macrophytes, these metals were in the order as follows: Mn > As > Ni > Zn > Cr > Cd > Cu > Pb and As > Mn > Zn > Ni > Cr > Cd > Pb during summer and winter seasons respectively. Contamination degree (C) (1.023-5.309) for these lakes showed low contamination during both seasons; mC values (below 1.5) showed very little contamination degree, while the pollution load index (0.012 to 0.0386) indicated no metal pollution in these lakes. PCA applied on sediment showed that Pb, Zn, Cr, Cu, and Cd had anthropogenic sources of origin. As and Mn were due to natural processes while Ni could be resultant of both anthropogenic and natural sources. PCA on macrophytes showed that Ni, Pb, Cr, Zn, Cu; Cd, As; Mn had anthropogenic, natural, and anthropogenic + natural sources of origin. The study concluded that metal concentrations in sediments were not up to dangerous level.

摘要

湿地作为陆地的“肾脏”,通过水生植物的吸收作用,促进了金属和其他有害污染物的修复。本研究旨在调查乌恰利湿地复合体沉积物和植物中的金属浓度、金属来源以及污染水平。在夏季和冬季,从 15 个随机选择的地点采集了沉积物样本。使用电感耦合等离子体技术,在夏季和冬季分别测定了沉积物和大型植物中 Cd、Pb、Ni、Cu、Zn、Cr、As、Mn 等金属的浓度。夏季和冬季沉积物中金属浓度的顺序为:As > Mn > Zn > Cr > Ni > Cd > Pb > Cu 和 As > Mn > Zn > Cr > Ni > Pb > Cd > Cu。所有分析的金属均在欧盟(EU)限值内。在大型植物中,这些金属的顺序为:Mn > As > Ni > Zn > Cr > Cd > Cu > Pb 和 As > Mn > Zn > Ni > Cr > Cd > Pb 在夏季和冬季。这些湖泊的污染程度(C)(1.023-5.309)在两个季节均显示出低污染程度;mC 值(低于 1.5)表明污染程度很小,而污染负荷指数(0.012 至 0.0386)表明这些湖泊没有金属污染。对沉积物进行的 PCA 表明,Pb、Zn、Cr、Cu 和 Cd 具有人为来源。As 和 Mn 是由于自然过程,而 Ni 可能是人为和自然来源的结果。对大型植物进行的 PCA 表明,Ni、Pb、Cr、Zn、Cu;Cd、As;Mn 具有人为、自然和人为+自然来源。研究结论是,沉积物中的金属浓度没有达到危险水平。

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