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基于聚合物的海洋防污和防污释放表面:合成和修饰策略。

Polymer-Based Marine Antifouling and Fouling Release Surfaces: Strategies for Synthesis and Modification.

机构信息

Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, USA; email:

Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853, USA; email:

出版信息

Annu Rev Chem Biomol Eng. 2019 Jun 7;10:241-264. doi: 10.1146/annurev-chembioeng-060718-030401.

Abstract

In marine industries, the accumulation of organic matter and marine organisms on ship hulls and instruments limits performance, requiring frequent maintenance and increasing fuel costs. Current coatings technology to combat this biofouling relies heavily on the use of toxic, biocide-containing paints. These pose a serious threat to marine ecosystems, affecting both target and nontarget organisms. Innovation in the design of polymers offers an excellent platform for the development of alternatives, but the creation of a broad-spectrum, nontoxic material still poses quite a hurdle for researchers. Surface chemistry, physical properties, durability, and attachment scheme have been shown to play a vital role in the construction of a successful coating. This review explores why these characteristics are important and how recent research accounts for them in the design and synthesis of new environmentally benign antifouling and fouling release materials.

摘要

在海洋工业中,有机物和海洋生物在船体和仪器上的积累限制了其性能,需要频繁进行维护并增加燃料成本。目前,用于对抗生物污垢的涂层技术严重依赖于使用含有有毒杀菌剂的涂料。这些涂料对海洋生态系统构成了严重威胁,影响了目标和非目标生物。聚合物设计的创新为替代品的开发提供了一个极好的平台,但要开发出广谱、无毒的材料,对研究人员来说仍然是一个相当大的挑战。表面化学、物理性质、耐久性和附着方案已被证明在成功涂层的构建中起着至关重要的作用。本综述探讨了为什么这些特性很重要,以及最近的研究如何在新的环保型防污和自清洁材料的设计和合成中考虑到这些特性。

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