氧化还原调控的α-硝基烷基自由基与苯乙烯的光催化加成反应的分歧。
Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes.
机构信息
Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8601, Japan.
出版信息
Chem Commun (Camb). 2020 Sep 22;56(75):11014-11017. doi: 10.1039/d0cc04821f.
PMID:32785394
Abstract
A divergent photocatalytic system for the reaction of α-bromo nitroalkanes with styrene derivatives is established, wherein the generation of the persistent nitroxyl radical as a junctional intermediate and suitable tuning of the redox ability of the system constitute the crucial elements for achieving rigorous control over the possible reaction pathways.
摘要
建立了一种用于α-溴代硝基烷烃与苯乙烯衍生物反应的歧化光催化体系，其中持久的氮氧自由基的生成作为连接中间体，以及对体系氧化还原能力的适当调节是实现对可能反应途径进行严格控制的关键因素。
Zotero 插件