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晋江河口(中国福建)修复红树林湿地表层沉积物中的微塑料和积累的重金属。

Microplastics and accumulated heavy metals in restored mangrove wetland surface sediments at Jinjiang Estuary (Fujian, China).

机构信息

Department of Environmental Science and Engineering, College of Chemical Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Institute of Environmental and Resources Technology, Huaqiao University, Xiamen 361021, China.

Department of Environmental Science and Engineering, College of Chemical Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Institute of Environmental and Resources Technology, Huaqiao University, Xiamen 361021, China.

出版信息

Mar Pollut Bull. 2020 Oct;159:111482. doi: 10.1016/j.marpolbul.2020.111482. Epub 2020 Jul 27.

Abstract

Microplastics have received widespread attention as an emerging contaminant, but limited information was available during wetland restoration. The occurrence and characteristics of microplastics and their interaction with heavy metals in surface sediments from the Jinjiang Estuarine restored mangrove wetland were investigated. The abundance of microplastics ranged from 490 ± 127.3 to 1170 ± 99.0 items/500 g dry sediment, and the restored regions were much higher than mudflats, indicating mangrove restoration promoted its accumulation. Polyethylene terephthalate (PET), polyethylene (PE) and polypropylene (PP) were the main materials of microplastics after Raman spectroscopy identification. SEM-EDS images illustrated the mechanical erosion and chemical weathering on microplastics' surface, and Cr, Zn, Pb, and Cd were observed in elemental composition. The contents of Cr, Ni, Cu, Zn, Pb, As, and Cd accumulated in microplastics were not correlated with their total concentrations in sediments except for Hg, indicating that they might not be derived from sediments.

摘要

微塑料作为一种新兴污染物受到广泛关注,但在湿地恢复过程中,相关信息有限。本研究调查了晋江河口恢复红树林湿地表层沉积物中微塑料的分布特征及其与重金属的相互作用。微塑料的丰度范围为 490 ± 127.3 至 1170 ± 99.0 个/500 g 干沉积物,恢复区明显高于泥滩,表明红树林恢复促进了微塑料的积累。拉曼光谱鉴定结果表明,聚对苯二甲酸乙二醇酯(PET)、聚乙烯(PE)和聚丙烯(PP)是微塑料的主要材料。SEM-EDS 图像显示微塑料表面存在机械侵蚀和化学风化,元素组成中观察到 Cr、Zn、Pb 和 Cd。除 Hg 外,微塑料中 Cr、Ni、Cu、Zn、Pb、As 和 Cd 的含量与沉积物中的总浓度不相关,表明它们可能不是源自沉积物。

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