Department of Analytical Chemistry and Environmental Engineering, University Politehnica of Bucharest, 1-7 Polizu Str., 011061 Bucharest, Romania.
Horia Hulubei National Institute for R&D in Physics and Nuclear Engineering, 30 Reactorului Str., Magurele, 077125 Bucharest, Romania.
Molecules. 2021 Jun 10;26(12):3541. doi: 10.3390/molecules26123541.
In this manuscript an improved sorbent based on modified exfoliated carbon nanoplatelets, applied in the removal of ammonium from aqueous samples, is presented. This sorbent showed better efficiency in comparison with the previous one obtained in our group for ammonium removal, the values of the maximum sorption capacity being improved from 10 to 12.04 mg/g. In terms of kinetics and sorption characteristic parameters, their values were also improved. Based on these results, a sorption mechanism was proposed, taking into account ion-exchange and chemisorption processes at the surface of the oxidized exfoliated carbon nanoplatelets. Future applications for simultaneous removal of other positive charged contaminants from natural waters might be possible.
本文提出了一种基于改性剥离碳纳米片的改进吸附剂,用于去除水样中的铵。与我们之前报道的用于去除铵的吸附剂相比,这种吸附剂的效率更高,最大吸附容量从 10 提高到了 12.04mg/g。在动力学和吸附特征参数方面,它们的值也得到了提高。基于这些结果,提出了一种吸附机理,考虑了氧化剥离碳纳米片表面的离子交换和化学吸附过程。未来可能可以应用于从天然水中同时去除其他带正电荷的污染物。