Department of Chemical Engineering, Lambung Mangkurat University, Banjarbaru 70714, Indonesia.
Indonesian Institute of Science, Research Centre Chemistry, Tangerang 15314, Indonesia.
Molecules. 2021 Sep 28;26(19):5867. doi: 10.3390/molecules26195867.
The method of solvothermal by one-step operation has been performed to synthesize of magnetic amine-functionalized sugarcane bagasse biocomposites (SB-MH). The obtained SB-MH contains 62.34% of Fe, 17.8 mmol/g of amine, and a magnetic property of 19.46 emu/g. The biocomposite surface area increased significantly from 1.617 to 25.789 m/g after amine functionalization. The optimum condition of SB-MH used for Pb(II) ion removal was achieved at pH 5 for 360 min with adsorption capacity of 203.522 mg/g. The pseudo 2nd order was well-fitted to the model of Pb(II) ion adsorption. Meanwhile, other contaminant parameters number of Chemical Oxygen Demand (COD), Total Suspended Solid (TSS), and dye in wastewater were also remarkably reduced by about 74.4%, 88.0%, and 96.7%, respectively. The reusability of SB-MH with 4th repetitions showed only a slight decrease in performance of 5%. Therefore, the proposed magnetic amine-functionalized sugarcane bagasse biocomposites lead to a very potential adsorbent implemented in high scale due to high surface area, easy separation, stable materials and capability to adsorb contaminants from aqueous solution.
采用一步法溶剂热法合成了磁性胺功能化甘蔗渣生物复合材料(SB-MH)。所得到的 SB-MH 含有 62.34%的 Fe、17.8mmol/g 的胺基,具有 19.46emu/g 的磁性。胺功能化后,生物复合材料的比表面积从 1.617 显著增加到 25.789m/g。SB-MH 用于去除 Pb(II)离子的最佳条件是在 pH 5 下吸附 360min,吸附容量为 203.522mg/g。Pb(II)离子吸附的模型很好地符合伪二级动力学模型。同时,废水中的其他污染物参数化学需氧量(COD)、总悬浮固体(TSS)和染料的数量也分别显著减少了约 74.4%、88.0%和 96.7%。经过 4 次重复使用,SB-MH 的重复使用性能仅略有下降,为 5%。因此,由于具有高比表面积、易于分离、稳定的材料和从水溶液中吸附污染物的能力,所提出的磁性胺功能化甘蔗渣生物复合材料是一种非常有潜力的吸附剂,可以在大规模应用。