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高量子产率氮硼共掺杂碳点用于检测 Ag、生物成像和荧光墨水。

High quantum yield nitrogen and boron co-doped carbon dots for sensing Ag, biological imaging and fluorescent inks.

机构信息

School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, Shanxi, China.

State Key Laboratory of Food Science and Technology, Jiangnan University, Wuxi, 214122, Jiangsu, China.

出版信息

Anal Methods. 2021 Nov 25;13(45):5523-5531. doi: 10.1039/d1ay01582f.

Abstract

Herein, bright blue-green fluorescent nitrogen and boron co-doped carbon dots (N, B-CDs) with a quantum yield (QY) up to 33.04% were synthesized hydrothermal treatment from ammonium citrate tribasic and 3-aminophenylboronic acid. The synthesized N, B-CDs showed outstanding water solubility. According to the principle of the static quenching effect (SQE), the synthesized N, B-CDs were utilized as an efficient sensor for sensing Ag. The linear range and limit of detection (LOD) of the sensor for Ag are 0.99-26.04 μM and 9.03 nM (3/). The proposed method was successfully adopted to detect Ag in environmental water, which is of great significance to environmental detection. Furthermore, due to the excellent fluorescence performance, the N, B-CDs were found to be an effective tool for biological imaging and as a fluorescent ink, which widens the horizons for the multifunctional applications of N, B-CDs.

摘要

本文通过水热法由柠檬酸三铵和 3-氨基苯硼酸合成了具有高达 33.04%量子产率的亮蓝色荧光氮、硼共掺杂碳点(N,B-CDs)。所合成的 N,B-CDs 具有优异的水溶性。根据静态猝灭效应(SQE)原理,将合成的 N,B-CDs 用作检测 Ag 的高效传感器。该传感器对 Ag 的线性范围和检测限(LOD)分别为 0.99-26.04 μM 和 9.03 nM(3/)。该方法成功地用于检测环境水中的 Ag,这对环境检测具有重要意义。此外,由于优异的荧光性能,N,B-CDs 被发现是生物成像的有效工具,并且作为荧光墨水,拓宽了 N,B-CDs 的多功能应用前景。

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