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基于密度对道路扬尘中轮胎-道路磨损颗粒进行分类与表征

Classification and Characterization of Tire-Road Wear Particles in Road Dust by Density.

作者信息

Jung Uiyeong, Choi Sung-Seen

机构信息

Department of Chemistry, Sejong University, 209 Neungdong-ro, Gwangjin-gu, Seoul 05006, Korea.

出版信息

Polymers (Basel). 2022 Mar 2;14(5):1005. doi: 10.3390/polym14051005.

Abstract

Tire treads are abraded by friction with the road surface, producing tire tread wear particles (TWPs). TWPs combined with other particles on the road such as road wear particles (RWPs) and mineral particles (MPs), forming tire-road wear particles (TRWPs). Dust on an asphalt pavement road is composed of various components such as TRWPs, asphalt pavement wear particles (APWPs), MPs, plant-related particles (PRPs), and so on. TRWPs have been considered as one of major contaminants produced by driving and their properties are important for study on real abrasion behaviors of tire treads during driving as well as environmental contamination. Densities of the TRWPs are totally dependent on the amount of the other components deposited in the TWPs. In this study, a classification method of TRWPs in the road dust was developed using density separation and the classified TRWPs were characterized using image analysis and pyrolytic technique. Chloroform was used to remove APWPs from mixture of TRWPs and APWPs. TRWPs were found in the density range of 1.20-1.70 g/cm. By decreasing the particle size of the road dust, the TRWP content in the road dust increased and its density slightly tended to increase. Aspect ratios of the TRWPs varied and there were many TRWPs with low aspect ratio below 2.0. The aspect ratio range was 1.2-5.2. Rubber compositions of the TRWPs were found to be mainly NR/SBR biblend or NR/BR/SBR triblend.

摘要

轮胎胎面与路面摩擦会产生磨损,形成轮胎胎面磨损颗粒(TWPs)。TWPs与路面上的其他颗粒,如道路磨损颗粒(RWPs)和矿物颗粒(MPs)结合,形成轮胎-道路磨损颗粒(TRWPs)。沥青路面上的灰尘由TRWPs、沥青路面磨损颗粒(APWPs)、MPs、植物相关颗粒(PRPs)等各种成分组成。TRWPs被认为是驾驶过程中产生的主要污染物之一,其特性对于研究轮胎胎面在行驶过程中的实际磨损行为以及环境污染具有重要意义。TRWPs的密度完全取决于TWPs中沉积的其他成分的数量。在本研究中,利用密度分离法开发了一种道路灰尘中TRWPs的分类方法,并采用图像分析和热解技术对分类后的TRWPs进行了表征。使用氯仿从TRWPs和APWPs的混合物中去除APWPs。发现TRWPs的密度范围为1.20 - 1.70 g/cm。通过减小道路灰尘的粒径,道路灰尘中TRWP的含量增加,其密度略有增加趋势。TRWPs的长径比各不相同,有许多长径比低于2.0的低长径比TRWPs。长径比范围为1.2 - 5.2。发现TRWPs的橡胶成分主要是天然橡胶/丁苯橡胶二元共混物或天然橡胶/顺丁橡胶/丁苯橡胶三元共混物

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4047/8912506/6a5d2af6ae7f/polymers-14-01005-g001.jpg

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