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一种可逆的、比色的、pH响应型吲哚基水凝胶及其在尿素检测中的应用。

A reversible, colorimetric, pH-responsive indole-based hydrogel and its application in urea detection.

作者信息

Wang Yan, Luo Xuan, Zhang Longfei, Zhang Shuai, Zhang Lin

机构信息

Research Center of Laser Fusion, China Academy of Engineering Physicals Mianyang 621900 P. R. China

出版信息

RSC Adv. 2019 Aug 6;9(42):24299-24304. doi: 10.1039/c9ra03815a. eCollection 2019 Aug 2.

Abstract

A new type of pH-responsive indole-based (4-HINF) hydrogel, fabricated by a sol-gel method, was utilized as a platform for colorimetric detection of urea in aqueous solution. The colorimetric sensor was established by virtue of the synergistic effect of cation-π interaction and hydrogen bonding with good regenerative ability. The results exhibited linear response in the range of 0-10 mM with a limit of detection of 10 μM. The prepared 4-HINF hydrogel possessed high selectivity to pH change under complicated environments ensuring further applications in environmental and bio-systems.

摘要

一种通过溶胶-凝胶法制备的新型pH响应性吲哚基(4-HINF)水凝胶被用作水溶液中尿素比色检测的平台。该比色传感器是通过阳离子-π相互作用和氢键的协同效应建立的,具有良好的再生能力。结果表明在0-10 mM范围内呈线性响应,检测限为10 μM。所制备的4-HINF水凝胶在复杂环境下对pH变化具有高选择性,确保了在环境和生物系统中的进一步应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbdb/9069612/6e5d36df0952/c9ra03815a-f1.jpg

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