Wei Zhi-Li, Wang Lan, Guo Shuang-Zhu, Zhang Yang, Dong Wen-Kui
College of Chemical and Biological Engineering, Lanzhou Jiaotong University Lanzhou Gansu 730070 China
RSC Adv. 2019 Dec 13;9(70):41298-41304. doi: 10.1039/c9ra09017g. eCollection 2019 Dec 9.
In this paper, a salamo-based copper(ii) complex probe L-Cu was synthesized, which combined with copper(ii) ions to form L-Cu for the detection of S and had a good fluorescence chemical response. Through spectral analysis, we found that S could be identified with high sensitivity and selectivity in the presence of various anions and could be used for the detection of S by the naked eye. With the addition of S, the solution color changed from colorless to bright yellow. UV absorption, fluorescence and other characterization methods were carried out, and the mechanism of action was determined. In addition, we performed a visual inspection of HS gas, and the probe L-Cu could detect S in the gas molecules, revealing its potential application value in biology and medicine.
本文合成了一种基于萨拉莫的铜(II)配合物探针L-Cu,其与铜(II)离子结合形成L-Cu用于检测硫(S),并具有良好的荧光化学响应。通过光谱分析,我们发现S在各种阴离子存在下能够以高灵敏度和选择性被识别,并且可以通过肉眼用于检测S。加入S后,溶液颜色从无色变为亮黄色。进行了紫外吸收、荧光等表征方法,并确定了作用机制。此外,我们对硫化氢(HS)气体进行了目视检测,探针L-Cu能够检测气体分子中的S,揭示了其在生物医学中的潜在应用价值。