关于Criegee中间体反应活性的开放性问题。
Open questions on the reactivity of Criegee intermediates.
作者信息
Caravan Rebecca L, Vansco Michael F, Lester Marsha I
机构信息
Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL, USA.
Department of Chemistry, University of Pennsylvania, Philadelphia, PA, USA.
出版信息
Commun Chem. 2021 Mar 25;4(1):44. doi: 10.1038/s42004-021-00483-5.
Abstract
Criegee intermediates are reactive intermediates formed in Earth’s atmosphere through ozonolysis of alkenes. Here the authors outline the fundamental chemistry that influences their highly conformer- and substituent-dependent unimolecular and bimolecular reactivity, and discuss open questions of fundamental and atmospheric interest.
摘要
克里吉中间体是通过烯烃在地球大气中的臭氧分解反应形成的活性中间体。本文作者概述了影响其高度依赖构象体和取代基的单分子及双分子反应活性的基础化学，并讨论了具有基础研究意义和大气研究意义的开放性问题。
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